推荐产品
品質等級
化驗
98%
形狀
liquid
折射率
n20/D 1.446 (lit.)
bp
128-130 °C/12 mmHg (lit.)
密度
0.994 g/mL at 25 °C (lit.)
官能基
allyl
ester
SMILES 字串
CCOC(=O)C(CC=C)(CC=C)C(=O)OCC
InChI
1S/C13H20O4/c1-5-9-13(10-6-2,11(14)16-7-3)12(15)17-8-4/h5-6H,1-2,7-10H2,3-4H3
InChI 密鑰
LYUUVYQGUMRKOV-UHFFFAOYSA-N
一般說明
报道了二烯丙基丙二酸二乙酯开环复分解反应的低催化剂负载量 。阳离子镍（以单戊酸亚磷酰胺和 Wilke 偶氮磷酸为配体）催化二乙基二烯丙基丙二酸酯的环异构化反应已有报告。
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
235.4 °F - closed cup
閃點（°C）
113 °C - closed cup
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
其他客户在看
![2,6-二异丙基苯基亚氨基-叔丁基亚苯基[(S)-(-)-BIPHEN]钼(VI) ringclosing metathesis catalyst, ≥95.0% (C)](/deepweb/assets/sigmaaldrich/product/structures/312/745/96ea840b-77a7-427a-9db5-fa08b3ffd45e/640/96ea840b-77a7-427a-9db5-fa08b3ffd45e.png)
Renat Kadyrov
Chemistry (Weinheim an der Bergstrasse, Germany), 19(3), 1002-1012 (2012-11-28)
An efficient procedure is described for ring-closing metathesis reactions. A conversion of 95% for diethyl diallylmalonate in dilute solution could be achieved within a few minutes, reaching TOF = 4173 min(-1), with very low loading of commercially available Ru catalysts that
Christian Böing et al.
Chemical communications (Cambridge, England), (11)(11), 1456-1458 (2005-03-10)
Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate.
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