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269905

Sigma-Aldrich

N , N -二甲基甲酰胺-d 7

≥99.5 atom % D, contains 1 % (v/v) TMS

别名:

DMF-d7, 二甲基甲酰胺(氘代)

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About This Item

线性分子式:
DCON(CD3)2
CAS号:
4472-41-7
分子量:
80.14
Beilstein:
1908468
MDL號碼:
MFCD00003286
分類程式碼代碼:
12142201
PubChem物質ID:
24856179

同位素純度

≥99.5 atom % D

品質等級

200

化驗

≥99% (CP)

形狀

liquid

包含

1 % (v/v) TMS

技術

NMR: suitable

折射率

n20/D 1.428 (lit.)

bp

153 °C (lit.)

密度

1.03 g/mL at 25 °C (lit.)

質量偏移

M+7

SMILES 字串

[2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D

InChI 密鑰

ZMXDDKWLCZADIW-YYWVXINBSA-N

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應用


  • Investigation of the feasibility of directly-coupled HPLC-NMR with 2H detection: This research utilizes N,N-Dimethylformamide-d₇ to enhance the capabilities of HPLC-NMR systems, providing a methodological breakthrough for analyzing the metabolism of complex molecules in pharmaceutical sciences. This advancement is critical for the development of new drugs and understanding their metabolic pathways (Farrant RD et al., 1997).

  • Deuterium NMR spectroscopy of biofluids for the identification of drug metabolites: Applies N,N-Dimethylformamide-d₇ in deuterium NMR spectroscopy to identify and analyze drug metabolites in biological fluids. This technique provides a high-resolution method for drug testing and toxicological studies, enhancing the accuracy and efficiency of pharmaceutical research (Farrant RD et al., 1993).

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訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

136.4 °F - closed cup

閃點（°C）

58 °C - closed cup

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NMR determination of quadrupole coupling constants of deuterons in N, N-dimethylformamide-d7.
Balakrishnan NS.
Journal of Magnetic Resonance, 83(2), 233-245 (1989)
Neutron diffraction study on chloride ion solvation in water, methanol, and N,N-dimethylformamide.
Yamagami M, et al.
J. Chem. Phys., 103(18), 8174-8178 (1995)
Małgorzata Fabijańska et al.
Dalton transactions (Cambridge, England : 2003), 44(3), 938-947 (2014-08-12)
This paper describes the synthesis of trans-bis-(3-aminoflavone)dichloridoplatinum(ii) (trans-Pt(3-af)2Cl2; TCAP) for use as a potential anticancer compound, and the evaluation of its structure by elemental and spectral analyses, and X-ray crystallography. The complex demonstrated a significant cytotoxic effect against human and
Seung Bin Baek et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(46), 14156-14161 (2015-11-19)
Crystallographic observation of adsorbed gas molecules is a highly difficult task due to their rapid motion. Here, we report the in situ single-crystal and synchrotron powder X-ray observations of reversible CO2 sorption processes in an apparently nonporous organic crystal under
Sean E Doris et al.
Journal of the American Chemical Society, 136(44), 15702-15710 (2014-10-11)
Cationic naked nanocrystals (NCs) are useful building units for assembling hierarchical mesostructured materials. Until now, their preparation required strongly electrophilic reagents that irreversibly sever bonds between native organic ligands and the NC surface. Colloidal instabilities can occur during ligand stripping

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