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Merck

252581

Sigma-Aldrich

2-苯乙硫醇

98%

别名:

β-苯基乙硫醇, 苯乙硫醇

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About This Item

线性分子式:
C6H5CH2CH2SH
CAS号:
分子量:
138.23
Beilstein:
1446618
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

折射率

n20/D 1.560 (lit.)

bp

217-218 °C (lit.)

密度

1.032 g/mL at 25 °C (lit.)

官能基

phenyl
thiol

SMILES 字串

SCCc1ccccc1

InChI

1S/C8H10S/c9-7-6-8-4-2-1-3-5-8/h1-5,9H,6-7H2

InChI 密鑰

ZMRFRBHYXOQLDK-UHFFFAOYSA-N

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一般說明

2-苯乙硫醇在有机合成中作为合成砌块,用于将巯基功能基团引入分子中。已经使用共振双光子电离光谱法研究了 2-苯基乙硫醇及其 1:1 水分子团簇结构

應用

2-苯基乙硫醇已用于:
  • 制备用各种类型的硫醇配体保护的双二十面体 Au(25)簇
  • 作为肽的磷酸化序列的衍生化试剂,用于提高基质辅助激光解吸/电离质谱中的电离效率

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

194.0 °F - closed cup

閃點(°C)

90 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Clementine Klemm et al.
Rapid communications in mass spectrometry : RCM, 18(22), 2697-2705 (2004-10-16)
The identification of phosphorylation sites is essential for a full understanding of the cellular functions of proteins. However, mass spectrometric analysis is often hampered by the low abundance of phosphoproteins, the difficulty of obtaining full sequence coverage by specific proteolysis
SunYoung Park et al.
Langmuir : the ACS journal of surfaces and colloids, 28(17), 7049-7054 (2012-04-12)
The synthesis and electrochemical and spectroscopic characterization of biicosahedral Au(25) clusters with a composition of [Au(25)(PPh(3))(10)(thiolate)(5)Cl(2)](2+) are described. The biicosahedral Au(25) clusters protected with various types of thiol ligands including alkanethiols, 2-phenylethanethiol, 11-mercaptoundecanoic acid, and 11-mercapto-1-undecanol were synthesized in high
Danielle E Martin et al.
The Journal of chemical physics, 128(16), 164301-164301 (2008-05-02)
The structures of 2-phenylethanethiol (PET, PhCH(2)CH(2)SH) and its 1:1 water clusters have been studied using resonant two-photon ionization spectroscopy including band contour analysis and UV-UV holeburning, combined with extensive ab initio calculations on ground and excited states. The most populated
Shubo Tian et al.
Nature communications, 6, 8667-8667 (2015-10-21)
Revealing structural isomerism in nanoparticles using single-crystal X-ray crystallography remains a largely unresolved task, although it has been theoretically predicted with some experimental clues. Here we report a pair of structural isomers, Au38T and Au38Q, as evidenced using electrospray ionization
Alif Chebbi et al.
FEMS microbiology letters, 362(14) (2015-06-19)
Hydrogen sulfide (H2S) and thiols (RSH) generated by the phosphate industry cause harmful effects on human health and quality of life. The present study aims to investigate and evaluate a bacterial strain CAT37 isolated from gas-washing wastewaters in terms of

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Self-assembled monolayers (SAMs) have attracted enormous interest for a wide variety of applications in micro- and nano-technology. In this article, we compare the benefits of three different classes of SAM systems (alkylthiolates on gold.

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