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Merck

248592

Sigma-Aldrich

硝酸铋(III) 五水合物

reagent grade, 98%

别名:

Bismuth trinitrate pentahydrate

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About This Item

线性分子式:
Bi(NO3)3 · 5H2O
CAS号:
分子量:
485.07
EC號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

等級

reagent grade

品質等級

化驗

98%

形狀

crystals

反應適用性

core: bismuth
reagent type: catalyst

bp

75-80 °C (lit.)

mp

30 °C (lit.)

SMILES 字串

O=[N+](O[Bi](O[N+]([O-])=O)O[N+]([O-])=O)[O-].C

InChI

1S/CH4.Bi.3NO3/c;;3*2-1(3)4/h1H4;;;;/q;+3;3*-1

InChI 密鑰

DPLOIMSBRDLLRI-UHFFFAOYSA-N

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一般說明

硝酸铋(III) 五水合物是水合形式的硝酸铋(III)。它可作为有效的路易斯酸催化剂用于硫代羰基转化为羰基化合物的有机合成反应;芳香硝化反应;羰基化合物的保护;Michael反应和香豆素的合成。

應用

各种 4-取代的 Hantzsch 1,4-二氢吡啶的优质氧化剂。将硫化物选择性氧化成亚砜的简便试剂。

象形圖

Flame over circleCorrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Ox. Sol. 2

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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Mashraqui, S.H. Karnik, M.A.
Synthesis, 713-713 (1998)
Mashraqui, S.H. et al.
Synthetic Communications, 28, 939-939 (1998)
Na Li et al.
Dalton transactions (Cambridge, England : 2003), 43(36), 13742-13750 (2014-08-12)
The xFe2O3/yBiOCl composites (xFe/yBi, x/y = 0/100, 5/100, 10/100, 20/100, 30/100 and 40/100 molar ratios) are prepared for the first time through an in situ hydrolysis method under hydrothermal conditions. The samples are characterized by X-ray diffraction (XRD), scanning electron
Nahid Gharib Naseri et al.
Analytical and bioanalytical chemistry, 391(4), 1283-1292 (2008-03-21)
Catalytic adsorptive stripping voltammetry (CAdSV) has been demonstrated at a bismuth film electrode (BiFE) in an injection-moulded electrochemical micro-flow cell. The polystyrene three-electrode flow cell was fabricated with electrodes moulded from a conducting grade of polystyrene containing 40% carbon fibre
Marcela Luísa Gomes et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 20(5), 771-779 (2015-05-02)
Two bismuth(III) porphyrins-5,10,15,20-tetrakis(phenyl)porphyrinatobismuth(III) nitrate, [Bi(III)(TPP)]NO3, and the unprecedent 5,10,15,20-tetrakis(4-carbomethoxyphenyl)porphyrinatobismuth(III) nitrate, [Bi(III)(T4CMPP)]NO3, and two unprecedented antimony(V) porphyrins dichlorido(5,10,15,20-tetrakis(phenyl)porphyrinato)antimony(V) bromide, [Sb(V)(TPP)Cl2]Br, and dibromido(5,10,15,20-tetrakis(4-carbomethoxyphenyl)porphyrinato)antimony(V) bromide, [Sb(V)(T4CMPP)Br2]Br,-were synthesized by reacting the corresponding porphyrin ligand with Bi(NO3)3·5H2O or SbCl3. All compounds were characterized by UV-vis

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