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242306

Sigma-Aldrich

氯甲酸烯丙酯

97%, for peptide synthesis

别名:

2-Propen-1-yl chloroformate, Allyloxycarbonyl chloride

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About This Item

线性分子式:
ClCOOCH2CH=CH2
CAS号:
2937-50-0
分子量:
120.53
Beilstein:
773915
EC號碼:
220-916-6
MDL號碼:
MFCD00000648
分類程式碼代碼:
12190000
PubChem物質ID:
24854549
NACRES:
NA.22

产品名称

氯甲酸烯丙酯, 97%

蒸汽壓力

3.67 psi ( 20 °C)

品質等級

200

化驗

97%

形狀

liquid

折射率

n20/D 1.422 (lit.)

bp

~27 °C/11 mmHg (lit.)

密度

1.134 g/mL at 20 °C (lit.)

應用

peptide synthesis

儲存溫度

−20°C

SMILES 字串

ClC(=O)OCC=C

InChI

1S/C4H5ClO2/c1-2-3-7-4(5)6/h2H,1,3H2

InChI 密鑰

CAEWJEXPFKNBQL-UHFFFAOYSA-N

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相关类别

一般說明

氯甲酸烯丙酯是一种有机化合物，用于合成各种化合物，如烯丙基氨基甲酸酯和烯丙基碳酸酯。此外，它可用于制备α-烯丙基羰基和α, β-不饱和羰基。

應用

氯甲酸烯丙酯可用于合成：
  • 组蛋白及其类似物。
  • 由环硫酯(d,l-高半胱氨酸 硫内脂盐酸盐)生成Alloc-TL单体 (N-(烯丙氧基)羰基高半胱氨酸硫代内酯) 。

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 3 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

87.8 °F - closed cup

閃點（°C）

31 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBN4259
SHBN2550
SHBM4450
SHBM0749
SHBL8870

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Angewandte Chemie (International ed. in English), 46(21), 3966-3970 (2007-04-20)
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Journal of the mechanical behavior of biomedical materials, 87, 148-154 (2018-08-03)
Over the past years, significant effort has been dedicated to synthesizing low-shrinking formulations, however, development of dental composites with low volumetric shrinkage continues to be challenging. The purpose of this study was to synthesize a bisphenol allylic derivate (BPhADAC) and
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Nucleosides, nucleotides & nucleic acids, 27(8), 901-913 (2008-08-13)
Degradation of clofarabine (3) in 0.9% saline solution at 100 degrees C afforded three degradation products which were determined to be formamidopyrimidines 4-6. Compounds 4 and 5 were assigned as C(1') anomers on the basis of one-dimensional and two-dimensional NMR
[Toxic action of allylchloroformate].
E F Oskerko et al.
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Nature communications, 9(1), 1680-1680 (2018-04-28)
Bacteria preferentially accumulating in tumor microenvironments can be utilized as natural vehicles for tumor targeting. However, neither current chemical nor genetic approaches alone can fully satisfy the requirements on both stability and high efficiency. Here, we propose a strategy of
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