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208523

Sigma-Aldrich

三氯化钌

Ru content 45-55%

别名:

Ruthenium trichloride

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About This Item

线性分子式:
RuCl3
CAS号:
10049-08-8
分子量:
207.43
EC號碼:
233-167-5
MDL號碼:
MFCD00011208
分類程式碼代碼:
12161600
PubChem物質ID:
24852520
NACRES:
NA.22

形狀

solid

反應適用性

core: ruthenium
reagent type: catalyst
reaction type: Atom Transfer Radical Polymerization (ATRP)

密度

3.11 g/mL at 25 °C (lit.)

SMILES 字串

Cl[Ru](Cl)Cl

InChI

1S/3ClH.Ru/h3*1H;/q;;;+3/p-3

InChI 密鑰

YBCAZPLXEGKKFM-UHFFFAOYSA-K

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相关类别

一般說明

氯化钌（III）是一种化合物，它可用作温和的路易斯酸催化剂，用于醛的缩醛化、醇的缩醛化和酮肟向酰胺的转化。 此外，它也可作为前体用于合成钌纳米颗粒。

應用

氯化钌（III）可用作以下反应的催化剂：：

  • 通过环氧化物与苯胺的亲核开环反应合成β‐氨基醇。
  • 在温和条件下各种酚、醇、硫醇和胺的乙酰化反应。
  • 通过混合醛、胺和三甲基氰硅烷合成α‐氨基腈。

其他說明

不溶物形式

訊號詞

Danger

危險聲明

H302,H314,H411

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8B - Non-combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Patrik Västilä et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(12), 3218-3225 (2006-01-28)
We studied the role of alkali cations in the [{RuCl2(p-cymene)}2]-pseudo-dipeptide-catalyzed enantioselective transfer hydrogenation of ketones with isopropanol. Lithium salts were shown to increase the enantioselectivity of the reaction when iPrONa or iPrOK was used as the base. Similar transfer-hydrogenation systems
Tetrahedron Letters, 48, 5131-5131 (2007)
Yoshihiko Yamamoto et al.
Organic & biomolecular chemistry, 3(9), 1768-1775 (2005-04-29)
In the presence of catalytic amounts of Cp*RuCl(cod), the partially intramolecular cyclotrimerizations of various C-alkynylglycosides and C-diynylglycosides proceeded at ambient temperature to afford C-arylglycosides.
Jong Seok Lee et al.
The Journal of organic chemistry, 72(15), 5820-5823 (2007-06-26)
Ruthenium-catalyzed site-specific C-H oxyfunctionalization of steroidal ethers with periodate or bromate as terminal oxidants in phosphate buffer provided the acid-sensitive C-16 hydroxy compounds in high yields. Phosphate buffer (pH 7.5) significantly inhibits formation of unwanted side products generated under more
Sébastien Perdriau et al.
ChemSusChem, 5(12), 2427-2434 (2012-10-13)
Cardanol, a constituent of cashew nutshell liquid (CNSL), was subjected to transfer hydrogenation catalyzed by RuCl(3) using isopropanol as a reductant. The side chain of cardanol, which is a mixture of a triene, a diene, and a monoene, was selectively
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