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Merck
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文件

203491

Sigma-Aldrich

氯化铱(III) 水合物

99.9% trace metals basis

别名:

三氯化铱 水合物

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About This Item

线性分子式:
IrCl3 · xH2O
CAS号:
14996-61-3
分子量:
298.58 (anhydrous basis)
EC號碼:
233-044-6
MDL號碼:
MFCD00149749
分類程式碼代碼:
12352302
PubChem物質ID:
24852176
NACRES:
NA.23

化驗

99.9% trace metals basis

形狀

crystals and lumps

反應適用性

reagent type: catalyst
core: iridium

雜質

≤1500.0 ppm Trace Metal Analysis

密度

5.3 g/mL at 25 °C (lit.)

SMILES 字串

[H]O[H].Cl[Ir](Cl)Cl

InChI

1S/3ClH.Ir.H2O/h3*1H;;1H2/q;;;+3;/p-3

InChI 密鑰

MJRFDVWKTFJAPF-UHFFFAOYSA-K

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相关类别

一般說明

Iridium(III) chloride hydrate is a dark green to black hygroscopic solid that is widely used as a Ir source/precursor to synthesize Ir nanoparticle and battery materials.

應用

Iridium(III) chloride hydrate can be used:
  • As a precursor to synthesize IrO2 nanofibrous catalyst for oxygen evolution reaction.
  • As a starting material to prepare Ir complex that acts as an additive to hole transport layer in perovskite solar cells. This Ir complex helps to reduce recombination rate and enhances the stability of solar cells.
  • To fabricate thin and highly active IrO2 anodes for proton exchange membrane electrolyzer cells (PEMECs).
  • As a precursor to synthesize ionic Ir metal complexes for efficient flexible green light-emitting electrochemical cells. This leads to enhanced quantum efficiency and luminescence.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H319

防範說明

P305 + P351 + P338

危險分類

Eye Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Ultrabright oxygen optodes based on cyclometalated iridium (III) coumarin complexes.
Borisov SM and Klimant I
Analytical Chemistry, 79(19), 7501-7509 (2007)
Shaped Ir?Ni bimetallic nanoparticles for minimizing Ir utilization in oxygen evolution reaction.
Lim J,et al.
Chemical Communications (Cambridge, England), 52(32), 5641-5644 (2016)
Maximilian Moser et al.
Angewandte Chemie (International ed. in English), 53(33), 8628-8633 (2014-06-04)
Rutile TiO2 is a heavily investigated oxide with, to date, scarce applications in industrial catalysis. The inactivity of this material in oxidations has been related to its inability to dissociate molecular oxygen. Herein we show how rutile catalyzes the oxidation
Ann M Rajnicek et al.
Advanced healthcare materials, 7(17), e1800473-e1800473 (2018-07-06)
Innovative neurostimulation therapies require improved electrode materials, such as poly(3,4-ethylenedioxythiophene) (PEDOT) polymers or IrOx mixed ionic-electronic conductors and better understanding of how their electrochemistry influences nerve growth. Amphibian neurons growing on transparent films of electronic (metal) conductors and electronic-ionic conductors

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