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195359

对氟三氟甲苯

Name: 对氟三氟甲苯
Brand: ALDRICH

98%

别名:

α,α,α,4-四氟甲苯

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About This Item

线性分子式:

FC₆H₄CF₃

CAS号:

402-44-8

分子量:

164.10

EC號碼:

206-944-1

MDL號碼:

MFCD00000399

分類程式碼代碼:

12352100

PubChem物質ID:

24851687

NACRES:

NA.22

品質等級

100

化驗

98%

形狀

liquid

折射率

n20/D 1.401 (lit.)

bp

102-105 °C (lit.)

mp

−42-−41.7 °C (lit.)

密度

1.293 g/mL at 25 °C (lit.)

SMILES 字串

Fc1ccc(cc1)C(F)(F)F

InChI

1S/C7H4F4/c8-6-3-1-5(2-4-6)7(9,10)11/h1-4H

InChI 密鑰

UNNNAIWPDLRVRN-UHFFFAOYSA-N

應用

对氟三氟甲苯可用于合成：

与2,2′-双酚经亲核芳香取代反应制备2,2′-双(三氟甲苯氧基)双苯
(S)-氟西汀，神经元血清素摄取的强效抑制剂
1-芳氧基-2-取代氨甲基四氢萘衍生物

象形圖

GHS02,GHS07

訊號詞

Danger

危險聲明

H225,H315,H319,H335

防範說明

P210 - P302 + P352 - P305 + P351 + P338

危險分類

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

51.8 °F - closed cup

閃點（°C）

11 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Synthesis and appetite suppressant activity of 1-aryloxy-2-substituted aminomethyltetrahydronaphthalenes as conformationally rigid analogues of fluoxetine.

Kalpana Bhandari et al.

Bioorganic & medicinal chemistry, 14(8), 2535-2544 (2005-12-13)

Several 1-aryloxy-2-substituted aminomethyltetrahydronaphthalenes (7-21) as conformationally rigid analogues of fluoxetine were synthesized and evaluated for their anorexigenic and antidepressant activities. For SAR studies the related acyclic analogues (22-27) were also prepared. Out of the 21 synthesized compounds, 10 compounds (9

Absolute configurations and pharmacological activities of the optical isomers of fluoxetine, a selective serotonin-uptake inhibitor.

D W Robertson et al.

Journal of medicinal chemistry, 31(7), 1412-1417 (1988-07-01)

Fluoxetine is a potent and selective inhibitor of the neuronal serotonin-uptake carrier and is a clinically effective antidepressant. Although fluoxetine is used therapeutically as the racemate, there appears to be a small but demonstrable stereospecificity associated with its interactions with

Synthesis of novel trifluoromethyl-bearing bifunctional acyl-acceptant arenes: 2,2'-bis(trifluoromethylated aryloxy)biphenyls.

Akiko Okamoto et al.

Journal of oleo science, 56(9), 479-491 (2007-09-28)

Novel bifunctional acyl-acceptant biphenyls bearing trifluoromethylated aroyloxy groups were successfully synthesized in high yields via TfOH-mediated electrophilic aromatic aroylation of fluorobenzene with CF(3)-bearing aroyl chlorides followed by nucleophilic aromatic substitution with 2,2'-biphenol. Similarly, 2,2'-bis(trifluoromethylphenoxy)biphenyl was synthesized via nucleophilic aromatic substitution

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