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![9-硼双环[3.3.1]壬烷 溶液 0.5 M in THF](/deepweb/assets/sigmaaldrich/product/structures/180/891/8b64e597-269d-4780-98b6-40889dfd06b9/640/8b64e597-269d-4780-98b6-40889dfd06b9.png)
形狀
liquid
品質等級
反應適用性
reagent type: reductant
濃度
1.0 M in hexanes
密度
0.675 g/mL at 25 °C
SMILES 字串
CCB(CC)CC
InChI
1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChI 密鑰
LALRXNPLTWZJIJ-UHFFFAOYSA-N
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應用
三乙基硼烷可用于：
- 在水介质中作为自由基反应的自由基引发剂和终止剂。（1）
- 通过与2-取代的烯丙基胂叶立德反应合成聚（2-取代-1-亚丙烯基）聚合物。（2）
作为催化剂用于：
N -杂环卡宾硼烷还原烷基溴的反应物
具有氧化电位的四甲基铵三烷基苯硼酸酯盐合成用反应物
- 醛的烯丙基化
- 脱羧酶 C-C 键断裂反应
- 氢化铼/硼路易斯酸共催化烯烃加氢反应
- 不饱和肟醚的区域选择性羟基烷基化
N -杂环卡宾硼烷还原烷基溴的反应物
具有氧化电位的四甲基铵三烷基苯硼酸酯盐合成用反应物
訊號詞
Danger
危險分類
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1A - STOT RE 1 Inhalation - STOT SE 3
標靶器官
Central nervous system, Nervous system
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類（WGK）
WGK 3
閃點（°F）
-32.8 °F
閃點（°C）
-36 °C
Synthesis of poly (2-substituted-1-propenylene)s from allylic arsonium ylides.
Mondiere R, et al.
Macromolecules, 38(3), 663-668 (2005)
Free-radical reaction of imine derivatives in water.
Miyabe H, et al.
The Journal of Organic Chemistry, 65(16), 5043-5047 (2000)
Hideto Miyabe et al.
Chemical & pharmaceutical bulletin, 51(5), 540-544 (2003-05-09)
Stereocontrol in radical reactions of oxime ether anchored to polymer support was studied. Highly diastereoselective solid-phase radical reaction was achieved by using triethylborane and diethylzinc as a radical initiator at low reaction temperature, providing a novel method for the synthesis
Masafumi Ueda
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 124(6), 311-319 (2004-06-01)
The aqueous medium radical reactions of a variety of imine derivatives such as oxime ether, oxime, hydrazone, nitrone, and N-sulfonylimine were investigated. Triethylborane-mediated intermolecular alkyl radical addition to glyoxylic oxime ether, oxime, and nitrone in water proceeded smoothly to give
Ken-ichi Yamada et al.
The Journal of organic chemistry, 77(3), 1547-1553 (2012-01-03)
Triethylborane-mediated tin-free radical alkylation of N-alkoxycarbonyl-imines, such as N-Boc-, N-Cbz-, and N-Teoc-imines, proceeded smoothly at a low temperature (-78 to -20 °C) to give the corresponding adducts in high yield. Although the formation of isocyanate was the major unfavorable reaction
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