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Merck

193992

Sigma-Aldrich

N,N-二甲基-对苯二胺

97%

别名:

4-氨基-N,N-二甲基苯胺, N,N-二甲基-1,4-苯二胺, DMPPDA, N,N-二甲基对苯二胺

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About This Item

线性分子式:
(CH3)2NC6H4NH2
CAS号:
分子量:
136.19
Beilstein:
508105
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.21

化驗

97%

形狀

solid

bp

262 °C (lit.)

mp

34-36 °C (lit.)

官能基

amine

SMILES 字串

CN(C)c1ccc(N)cc1

InChI

1S/C8H12N2/c1-10(2)8-5-3-7(9)4-6-8/h3-6H,9H2,1-2H3

InChI 密鑰

BZORFPDSXLZWJF-UHFFFAOYSA-N

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一般說明

N,N二甲基-p-苯二胺 (DPD, DMPD)是一种主要用作生产染料的芳香胺中间体。在存在铁(III)催化剂的情况下,其与H2O2的氧化反应已用于分光光度检测痕量铁(III)。研究人员已通过循环伏安法研究,对DMPD在各种pH下的电化学氧化进行了评估。据报道,在碱性条件下氧化的DMPD会发生水解分解。

應用

N,N二甲基-p-苯二胺可用于制备具有四氰基-p-醌二甲烷(TCNQ)的分子化合物。这些分子化合物的偏振吸收光谱已有报道。

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 1 Dermal - Acute Tox. 2 Oral - Acute Tox. 3 Inhalation

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

195.8 °F - closed cup

閃點(°C)

91 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Polarized Absorption Spectra of Single Crystals of Ion Radical Salts. I. Molecular Compounds of 7, 7, 8, 8-Tetracyano-p-quinodimethane with N, N, N', N'-Tetramethyl-p-phenylenediamine and N, N-Dimethyl-p-phenylenediamine.
Kuroda H, et al.
Bulletin of the Chemical Society of Japan, 41(12), 2855-2858 (1968)
An historical review of the use of dye precursors in the formulation of commercial oxidation hair dyes.
Corbett JF.
Dyes and Pigments, 41(1), 127-136 (1999)
Mechanism diversity in anodic oxidation of N, N-dimethyl-p-phenylenediamine by varying pH.
Maleki A and Nematollahi D.
Journal of Electroanalytical Chemistry, 704, 75-79 (2013)
Spectrophotometric catalytic determination of an ultratrace amount of iron (III) in water based on the oxidation of N, N-dimethyl-p-phenylenediamine by hydrogen peroxide.
Hirayama K and Unohara N.
Analytical Chemistry, 60(23), 2573-2577 (1988)
Erin L Willis et al.
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