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Merck

187240

Sigma-Aldrich

9-蒽甲醇

97%

别名:

9-(羟甲基)蒽

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About This Item

经验公式(希尔记法):
C15H12O
CAS号:
分子量:
208.26
Beilstein:
1873402
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

溶解度

chloroform: soluble 20 mg/mL, clear to slightly hazy, light yellow to yellow

官能基

hydroxyl

SMILES 字串

OCc1c2ccccc2cc3ccccc13

InChI

1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2

InChI 密鑰

JCJNNHDZTLRSGN-UHFFFAOYSA-N

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一般說明

9-蒽甲醇参与由氧化铝烷催化的L-丙交酯的开环聚合反应。它与-丁醇钾发生质子交换反应,生成9-蒽甲醇

9-蒽甲醇是蒽的衍生物,常用于Diels-Alder反应。

應用

9-蒽甲醇可用于:
  • 作为制备9-蒽甲基-1-哌嗪羧酸酯的起始原料,充当HPLC测定异氰酸酯的试剂。
  • Diels-Alder 反应,与二甲基乙炔-二羧酸酯反应生成内酯衍生物。
  • 作为δ-戊内酯开环聚合反应引发剂,合成聚((δ-戊内酯)。
  • 作为合成聚合物载体蒽的起始材料,在环加成反应中充当亲二烯体清除剂。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Development of a new approach for total isocyanate determination using the reagent 9-anthracenylmethyl-1-piperazinecarboxylate.
Roh Y-M, et al.
Analyst, 125(9), 1691-1696 (2000)
Shanshan Kou et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 96, 768-775 (2012-08-14)
Vibrational spectral measurements were made for 9-anthracenemethanol. Optimized geometrical structure and harmonic vibration frequencies were computed based on ab initio and density functional theory B3LYP methods using 6-311G(**) and LANL2DZ basis sets. The equilibrium geometries got from all of the
Chen-Yu Li et al.
Dalton transactions (Cambridge, England : 2003), 40(9), 1880-1887 (2011-02-02)
Aluminium complexes bearing sterically bulky benzotriazole-phenoxide ligands are synthesized and characterized structurally. The reaction of 2-(2H-benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol ((CMe2Ph)BTP-H) or 2-(2H-benzotriazol-2-yl)-4,6-di-tert-butylphenol ((t-Bu)BTP-H) with AlMe(3) (1.2 molar equiv.) in toluene yields [((CMe2Ph)BTP)AlMe(2)] (1) or [((t-Bu)BTP)AlMe(2)] (2) as a four-coordinated monomeric aluminium complex. Compound
Yasuhiro Ando et al.
Lipids, 42(10), 955-960 (2007-08-19)
This paper proposes a one-step method for preparation of fluorescent 9-anthrylmethyl esters from triacylglycerols (TAG) ranging in amount from 0.1 to 5 microg. It involves base-catalyzed transesterification using potassium 9-anthracenemethoxide, prepared by proton exchange between 9-anthracenemethanol and potassium tert-butoxide. Transesterification
J W Flesher et al.
Biochemical and biophysical research communications, 251(1), 239-243 (1998-10-29)
The role of electrophilic hydroxymethyl sulfate esters in the metabolic activation, DNA-damage, mutagenicity, and complete carcinogenicity of polycyclic aromatic hydrocarbons has been elucidated considerably in recent years. The observations are in agreement with a unified hypothesis which predicts that electrophilic

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