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Merck

187054

Sigma-Aldrich

4-溴苄醇

99%

别名:

(4-溴苯基)甲醇, (对溴苯基)甲醇, 1-(对溴苯基)甲醇, 1-溴-4-(羟甲基)苯, 4-羟甲基-1-溴苯, 对溴苯甲醇

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About This Item

线性分子式:
BrC6H4CH2OH
CAS号:
分子量:
187.03
Beilstein:
1931620
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

solid

mp

75-77 °C (lit.)

溶解度

dioxane: soluble 1 g/10 mL, clear to faintly turbid, colorless to faintly yellow

SMILES 字串

OCc1ccc(Br)cc1

InChI

1S/C7H7BrO/c8-7-3-1-6(5-9)2-4-7/h1-4,9H,5H2

InChI 密鑰

VEDDBHYQWFOITD-UHFFFAOYSA-N

基因資訊

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一般說明

4-溴苯甲醇与乙酰基二茂铁和芳基硼酸发生三组分反应,生成含有联芳基的二茂铁酮 。它在聚乙烯聚吡咯烷酮负载的过氧化氢、二氧化硅硫酸和溴化铵存在下发生氧化反应,生成 4-溴苯甲醛 。它与 1,1,1,3,3,3-六甲基二硅氮烷在催化剂量的天冬氨酸乙腈溶液中发生有效的三甲基硅烷化反应

應用

使用 4-溴苄醇合成:
  • 羟基末端功能化、取代聚芴
  • 聚(9,9-二十二烷基芴-2,7-二基)和聚(甲基丙烯酸羟乙酯)的三嵌段共聚物,对称棒状线圈

危險聲明

防範說明

危險分類

Aquatic Chronic 3

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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