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Merck

180629

Sigma-Aldrich

二苯基二硒醚

98%

别名:

二苯联硒

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About This Item

线性分子式:
C6H5SeSeC6H5
CAS号:
分子量:
312.13
Beilstein:
2047179
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

雜質

<2% diphenyl selenide

mp

59-61 °C (lit.)

SMILES 字串

[Se]([Se]c1ccccc1)c2ccccc2

InChI

1S/C12H10Se2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10H

InChI 密鑰

YWWZCHLUQSHMCL-UHFFFAOYSA-N

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一般說明

二苯二硒化物是一种有机硒化合物,是苯硒醇的氧化衍生物。它是苯基硒自由基的来源。它能与多种有机亲核试剂、亲电试剂和自由基反应。

應用

二苯二硒化物的用途:在铜铁氧体纳米颗粒催化剂的存在下,通过芳基卤化物与二苯二砷化物的交叉偶联合成硒化二芳基物。

生化/生理作用

二苯基二硒化物在体内抑制脑、肝和肾脏中的δ-氨基乙酰丙酸脱水酶(δ-ALA-D)。

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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E N Maciel et al.
Journal of biochemical and molecular toxicology, 14(6), 310-319 (2000-11-18)
In the present study, the inhibitory effect of diphenyl diselenide and diphenyl ditelluride after in vitro, acute (a single dose), or chronic exposure (14 doses) was examined in mice 24 hours after the last administration. In vitro, diphenyl diselenide, and
Marina Prigol et al.
Biological trace element research, 150(1-3), 272-277 (2012-06-14)
The purpose of this study was to provide data about in vivo tissue distribution and excretion of diphenyl diselenide ((PhSe)₂) in rats and mice through determination of selenium levels in different biological samples. (PhSe)₂ (500 mg/kg, dissolved in canola oil)
Claire M Weekley et al.
Biochemistry, 51(3), 736-738 (2012-01-17)
The selenoamino acids methylselenocysteine (MeSeCys) and selenomethionine (SeMet) have disparate efficacies as anticancer agents. Herein, we use X-ray absorption spectroscopy to determine the chemical form of selenium in human neuroblastoma cells. Cells treated with MeSeCys contain a significant diselenide component
César A Brüning et al.
Neurochemical research, 37(10), 2249-2258 (2012-08-01)
Cerebrovascular diseases, including ischemic stroke, are associated with high mortality worldwide. Oxidative stress and inflammation are important pathophysiological mechanisms involved in post-ischemic cerebral injury. The present study was designed to investigate the potential protective effect of diphenyl diselenide (PhSe)(2), an
Pengshang Zhou et al.
Nanoscale, 12(43), 22307-22316 (2020-11-05)
Transition metal dichalcogenides (TMDs) are gaining increasing interest in the field of lithium ion batteries due to their unique structure. However, previous preparation methods have mainly focused on their growth from substrates or by exfoliation of the bulk materials. Considering

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