155039

二苯基甲苯基磷

96%

• 别名: (4-Methylphenyl)diphenyl phosphine
• 线性分子式: (C₆H₅)₂PC₆H₄CH₃
• CAS号: 1031-93-2
• 分子量: 276.31
• EC號碼: 213-848-3
• MDL號碼: MFCD00008543
• 分類程式碼代碼: 12352002
• PubChem物質ID: 24849330
• NACRES: NA.22

属性

• 化驗: 96%
• 形狀: liquid
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 66-68 °C (lit.)
• 官能基: phosphine
• SMILES 字串: Cc1ccc(cc1)P(c2ccccc2)c3ccccc3
• InChI: 1S/C19H17P/c1-16-12-14-19(15-13-16)20(17-8-4-2-5-9-17)18-10-6-3-7-11-18/h2-15H,1H3
• InChI 密鑰: QJIMTLTYXBDJFC-UHFFFAOYSA-N

说明

應用

Reactant for:

• Three-component cyclization
• Probing coordination ability via a palladium pincer complex
• Chelation-assisted hydroacylation of olefins with primary alcohols

Reactant for synthesis of:

• Trinuclear ruthenium carbonyl triarylphosphine cluster complexes
• Leishmanicidal leads targeting mitochondria through inhibition of the respiratory complex
• InP nanofibers / metal phosphide nanostructures
• Peroxyl radical cations via pulse radiolysis one-electron oxidations

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves