推荐产品
品質等級
化驗
≥95.0%
溶解度
diethyl ether: 0.1 g/10 mL, clear, colorless
SMILES 字串
O=C1OC(=O)[C@H]2[C@@H]3C[C@@H](C=C3)[C@@H]12
InChI
1S/C9H8O3/c10-8-6-4-1-2-5(3-4)7(6)9(11)12-8/h1-2,4-7H,3H2/t4-,5+,6-,7+
InChI 密鑰
KNDQHSIWLOJIGP-UMRXKNAASA-N
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一般說明
双环[2.2.1]庚-5-烯-2,3-二羧酸酐可与甲基氨基甲基棕榈酸酯反应生成带有一个labdanoid取代基的双环[2.2.1]庚-1,2-二碳酸的酰胺。
應用
- 采用双环[2.2.1]-5-庚烯-2,3-二羧酸酐的可持续化学合成：Kharitonov等(2012)的研究探索了多萜类化合物(higher terpenoids)的合成转化，其中采用了双环[2.2.1]-5-庚烯-2,3-二羧酸酐。他们制备了新的细胞毒性试剂，贡献了一种可持续性的有机合成方法(Kharitonov et al., 2012)。
- 有机合成中间体：Birchall等(2021)研究了纳迪克酸酐，利用逆狄尔斯–阿尔德反应表明双环[2.2.1]-5-庚烯-2,3-二羧酸酐可用于高级有机实验室技术教学。并通过NMR研究进一步支持有机合成教育(Birchall et al., 2021)。
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Resp. Sens. 1 - Skin Sens. 1
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
其他客户在看
![双环[2.2.1]庚-5-烯-2-甲醛 95%](/deepweb/assets/sigmaaldrich/product/structures/420/624/80d9b7d0-cbbe-4841-b614-d06fdd69ba07/640/80d9b7d0-cbbe-4841-b614-d06fdd69ba07.png)
Iu V Kharitonov et al.
Bioorganicheskaia khimiia, 38(1), 127-136 (2012-07-17)
Condensation of methyl 16-aminomethyllambertianate with N-Boc-omega-amino acids leads smoothly to 16-(N-Boc-aminononan)- and 16-(N-Boc-aminoundecan)amidomethyllabdanoids. The amide of bicyclo[2.2.1]heptan-1,2-dicarbocylic acid with a labdanoid substituent was obtained under the reaction of methyl aminomethyllambertianate with bicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride. Intereaction of methyl 16-aminomethyllambertianate with chloroacetyl chloride
Richard Reece et al.
ACS applied materials & interfaces, 12(23), 25683-25692 (2020-05-15)
Considering the low specific capacitance of structural solid supercapacitors, which is due to the low ion diffusivity in solid electrolytes and the small specific surface area of some structural electrodes such as carbon fiber fabrics, novel structural supercapacitor designs are
An Yang et al.
Dental materials journal, 36(5), 560-565 (2017-06-02)
The aim of the study was to evaluate the effect of modifying polymethyl methacrylate (PMMA) denture base material with polyimide (PI) on its flexural property and biocompatibility. Low molecular weight (1,500 g/mol) PI was synthesized and small amount of PI
R Padhma Priya et al.
Journal of nanoscience and nanotechnology, 15(9), 6739-6746 (2015-12-31)
A new type of siloxane core modified phthalide cardo chain based polyimide (PI) was successfully prepared from siloxane core dianhydride and ether linked phenolphthalein diamine moiety. This PI was further modified with different weight percentages of multi-walled carbon nanotubes (MWCNTs)
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