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化驗
98%
形狀
powder
mp
102-106 °C (lit.)
SMILES 字串
Oc1ccc(Br)cc1C=O
InChI
1S/C7H5BrO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H
InChI 密鑰
MKKSTJKBKNCMRV-UHFFFAOYSA-N
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一般說明
5-溴水杨醛与1,2-双(4-氯-2-氨基苯氧基)乙烷反应，生成席夫碱配体1,2-双(2-(5-溴-2-羟基苯甲醛亚胺)-4-氯苯氧基)乙烷。这是合成二芳基氨基取代的N-甲基四氢salen配体的起始试剂。
5-溴水杨醛通常用于合成席夫碱和三苯基锡配合物。
5-溴水杨醛通常用于合成席夫碱和三苯基锡配合物。
應用
5-溴水杨醛可用于聚对苯二甲酸乙二醇酯（PET）薄膜和PET支架中胺定量过程中的化学衍生化。
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
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A diarylamino-substituted N-methyl tetrahydrosalen (salan) ligand, (An2N)LH(2), is prepared in four steps and overall 53% yield from 5-bromosalicylaldehyde, with the key step a palladium-catalysed Hartwig-Buchwald amination of the tert-butyldimethylsilyl-protected 5-bromo-N-methylsalan ligand. Reaction of (An2N)LH(2) or its bromo analogue with Ti(O(i)Pr)(4)
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The network of chemical reactions of 2,6-bis(5-bromo-2-hydroxybenzylidene)cyclohexanone (BHBC) when subjected to light and different pH values has been investigated. The pH dependent species involved in the chemical network have been identified and characterized by NMR and UV-VIS spectroscopy. Direct pH
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A new Schiff base ligand was synthesized by reaction of 5-bromosalicylaldehyde with 1,2-bis(4-chloro-2-aminophenoxy)ethane. Then the Schiff base complexes were synthesized by the reaction of metal salts and the novel Schiff base. The molar conductivity properties of the complexes were studied
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