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Merck

125504

Sigma-Aldrich

环丙胺

98%

别名:

氨基环丙烷

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About This Item

线性分子式:
C3H5NH2
CAS号:
分子量:
57.09
Beilstein:
741858
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽壓力

4.67 psi ( 20 °C)

品質等級

化驗

98%

形狀

liquid

自燃溫度

527 °F

折射率

n20/D 1.420 (lit.)

bp

49-50 °C (lit.)

密度

0.824 g/mL at 25 °C (lit.)

SMILES 字串

NC1CC1

InChI

1S/C3H7N/c4-3-1-2-3/h3H,1-2,4H2

InChI 密鑰

HTJDQJBWANPRPF-UHFFFAOYSA-N

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應用

环丙胺 (CPA) 用于 N -\ [4-(4-氟)苯基-2-氨基噻唑-5-基] 嘧啶-2-基-烷基胺衍生物的合成 。已用于合成 Pt (CPA) 2 甲硫亚甲基丙二酸酯)和 Pt (CPA) 2 乙基硫亚甲基丙二酸酯)配合物

生化/生理作用

环丙胺通过一种机制使细胞色素 P450 酶失活,该机制包括在氮气中先发生单电子氧化,然后环丙烷环断裂,导致酶的共价修饰 。它是 脱氮副球菌 中一种基于机制的喹啉甲胺脱氢酶抑制剂。

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

33.8 °F - closed cup

閃點(°C)

1 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles


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Synthesis and Antifungal Activity of 5-[2-(Alkylamino) pyrimidin-4-yl]-4-phenylthiazol-2-cycloalkylamine Derivatives on Phytophthora capsici.
Nam Sw, et al.
J. Korean Chem. Soc., 54(3), 395-402 (2011)
Coordination Mode vs. Anticancer Activity of the Platinum (II) Complexes Involving Sulfur-Containing Ylidenemalonate Ligands.
Sakai N, et al.
Bull. Korean Chem. Soc., 19(12), 1377-1379 (1998)
Dapeng Sun et al.
FEBS letters, 517(1-3), 172-174 (2002-06-14)
Cyclopropylamine is a mechanism-based inhibitor of the quinoprotein methylamine dehydrogenase (MADH) from Paracoccus denitrificans. The resulting inactivation is accompanied by the formation of a covalent cross-link between the alpha and beta subunits of MADH. The results of site-directed mutagenesis studies
Bram Denolf et al.
Organic letters, 9(2), 187-190 (2007-01-16)
Treatment of novel chiral N-sulfinyl alpha-chloro ketimines with Grignard reagents resulted in the synthesis of chiral N-(1-substituted cyclopropyl)-tert-butanesulfinamides in acceptable to good yields and diastereoselectivity via 1,3-dehydrohalogenation and subsequent addition of the Grignard reagent to the intermediate cyclopropylideneamine. Only in
Soda Chanthamath et al.
Organic letters, 15(4), 772-775 (2013-01-31)
The Ru(II)-Pheox-catalyzed asymmetric cyclopropanation of vinylcarbamates with diazoesters resulted in the corresponding cyclopropylamine derivatives in high yield and excellent diastereoselectivity (up to 96:4) and enantioselectivity (up to 99% ee).

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