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Merck

109975

Sigma-Aldrich

1,2-环氧丁烷

99%

别名:

1-丁烯氧化物, 乙基环氧乙烷, 氧化丁烯, 环氧丁烷

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About This Item

经验公式(希尔记法):
C4H8O
CAS号:
分子量:
72.11
Beilstein:
102411
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

蒸汽密度

2.2 (vs air)

品質等級

蒸汽壓力

140 mmHg ( 20 °C)

化驗

99%

自燃溫度

698 °F

expl. lim.

19 %

折射率

n20/D 1.384 (lit.)

bp

63 °C (lit.)

密度

0.829 g/mL at 25 °C (lit.)

SMILES 字串

CCC1CO1

InChI

1S/C4H8O/c1-2-4-3-5-4/h4H,2-3H2,1H3

InChI 密鑰

RBACIKXCRWGCBB-UHFFFAOYSA-N

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應用

1,2-环氧丁烷可用于:
  • 作为单体通过开环聚合反应合成新引发剂。 这些引发剂可用于制备复杂大分子,如接枝聚酰胺。
  • 聚乙烯亚胺的功能化,聚乙烯亚胺可用于合成CO2 捕集用的氧化稳定性吸附剂。

特點和優勢

  • 高可聚合性
  • 低转移反应易感性
  • 易处理

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

5.0 °F - closed cup

閃點(°C)

-15 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A M Rossi et al.
Teratogenesis, carcinogenesis, and mutagenesis, 3(1), 75-87 (1983-01-01)
In vivo and in vitro methodologies that have employed the yeast Schizosaccharomyces pombe as genetic indicator have been utilized to investigate the mutagenicity of two trichloroethylene (TCE) samples of pure and technical grade. Mutagenicity assays were also performed on two
G Sclar
Clinical neurology and neurosurgery, 101(3), 199-202 (1999-10-28)
A 19-year-old male developed complaints including weakness of the lower extremities and right hand, numbness, dysphagia and urinary difficulties following a 2 month exposure to an industrial solvent constituted mainly of 1-bromopropane, but also containing butylene oxide, 1,3 dioxolane, nitromethane
Quantitative determination of 1,2-butylene oxide in whole rat blood by gas chromatography-mass spectrometry.
P E Kastl et al.
Journal of chromatography, 398, 347-350 (1987-07-10)
D B McGregor et al.
Environmental and molecular mutagenesis, 13(3), 197-202 (1989-01-01)
Trichloroethylene (TCE) is a high production volume chemical frequently stabilized with oxiranes. These oxiranes may be responsible for the mutagenic activity of TCE in Salmonella, which has been occasionally, but not consistently, reported. High purity and oxirane-stabilized TCE samples were
T Nakamura et al.
Biochemical and biophysical research communications, 180(1), 124-130 (1991-10-15)
Halohydrin hydrogen-halide-lyase, which catalyzes the interconversion of halohydrins to epoxides, purified from a recombinant E. coli was found to catalyze the transformation of 1,2-epoxybutane into beta-hydroxyvaleronitrile in the presence of cyanide. Chloride inhibited competitively the formation of beta-hydroxyvaleronitrile. The enzyme

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