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67869

Sigma-Aldrich

4-Methylmorpholine

BioXtra, suitable for protein sequencing, ≥99.5% (GC)

Synonym(s):

NMM

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About This Item

Empirical Formula (Hill Notation):
C5H11NO
CAS Number:
109-02-4
Molecular Weight:
101.15
Beilstein:
102719
EC Number:
203-640-0
MDL number:
MFCD00006175
UNSPSC Code:
12191502
PubChem Substance ID:
57652111
NACRES:
NA.26

vapor density

>1 (vs air)

Quality Level

100

vapor pressure

18 mmHg ( 20 °C)

product line

BioXtra

Assay

≥99.5% (GC)

form

liquid

technique(s)

protein sequencing: suitable

impurities

with OPA-reagent reacting impuritites, none detected (fluorimetric)

refractive index

n20/D 1.435 (lit.)
n20/D 1.435

pH

10.6 (20 °C, 50 g/L)

bp

115-116 °C/750 mmHg (lit.)

mp

−66 °C (lit.)

density

0.92 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤5 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

absorption

cut-off at 290 nm

suitability

suitable for protein sequencing

SMILES string

CN1CCOCC1

InChI

1S/C5H11NO/c1-6-2-4-7-5-3-6/h2-5H2,1H3

InChI key

SJRJJKPEHAURKC-UHFFFAOYSA-N

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Application


  • Effect of morpholine, and 4-methylmorpholine on urethane formation: a computational study: This paper explores the role of 4-methylmorpholine in urethane synthesis, highlighting its utility in enhancing reaction efficiencies within computational models (Waleed et al., 2023).

  • Design, Synthesis, Characterization, and In Vitro Evaluation of a New Cross-Linked Hyaluronic Acid for Pharmaceutical and Cosmetic Applications: Incorporates 4-methylmorpholine in the design and synthesis of new hyaluronic acid formulations, underscoring its role in developing innovative pharmaceutical and cosmetic products (Sciabica et al., 2021).

Signal Word

Danger

Hazard Statements

H225,H302,H314

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

53.6 °F - closed cup - DIN 51755 Part 1

Flash Point(C)

12 °C - closed cup - DIN 51755 Part 1

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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V Kruft et al.
Analytical biochemistry, 193(2), 306-309 (1991-03-02)
Cysteine residues in polypeptides are not easily identified during automated N-terminal sequence analysis. Reaction of cysteine side chains with 4-vinylpyridine and identification as the pyridylethylated phenylthiohydantion derivative (PE-PTH-Cys) were proposed. However, after this reaction a desalting step is necessary. If
L Belin et al.
British journal of industrial medicine, 40(3), 251-257 (1983-08-01)
Investigations of respiratory symptoms among workers in a factory producing polyurethane foam included measurement of air pollution with amines and isocyanates and a simultaneous health investigation of the exposed workers. An increased bronchial reactivity to inhaled methacholine was found in
V Balachandran et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 97, 1101-1110 (2012-08-30)
The experimental FT-IR (4000-400 cm(-1)) and FT-Raman (3500-100 cm(-1)) spectra of 4-Methylmorpholine were recorded. The observed bands were interpreted with the aid of normal coordinate analysis and force field calculations based on density functional theory (DFT) using B3LYP functional theory
K Sitarek
Teratogenesis, carcinogenesis, and mutagenesis, 19(6), 369-376 (1999-12-10)
N-methylmorpholine, which is used as a catalyst in polyurethane foams producing, in solvents, stabilizing agents, and corrosion inhibitors, was administered to female rats by gavage at 100, 200, 600, and 900 mg/kg during organogenesis. It did not exhibit selective toxicity
L Hansén et al.
Scandinavian journal of work, environment & health, 12(1), 66-69 (1986-02-01)
The N-methylmorpholine levels in workroom air in a polyurethane foam factory were determined by two methods in which midget impinger flasks were used for sampling. The analyses were performed by gas chromatography and isotachophoresis. The values obtained by the gas
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