32824
Fluazifop
PESTANAL®, analytical standard
Synonym(s):
2-[4-(5-Trifluoromethyl-2-pyridyloxy)phenoxy]propionic acid
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About This Item
Empirical Formula (Hill Notation):
C15H12F3NO4
CAS Number:
Molecular Weight:
327.26
Beilstein:
552236
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24
Recommended Products
grade
analytical standard
Quality Level
product line
PESTANAL®
shelf life
limited shelf life, expiry date on the label
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
application(s)
agriculture
environmental
format
neat
SMILES string
CC(Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1)C(O)=O
InChI
1S/C15H12F3NO4/c1-9(14(20)21)22-11-3-5-12(6-4-11)23-13-7-2-10(8-19-13)15(16,17)18/h2-9H,1H3,(H,20,21)
InChI key
YUVKUEAFAVKILW-UHFFFAOYSA-N
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General description
Fluazifop is one of the major metabolites of fluazifop-p-butyl, a systemic, post-emergence herbicide used for the control of annual and perennial grass weeds in non-graminaceous crops.
Application
Fluazifop may be used as an analytical reference standard for the determination of the analyte in:
- Rainwater samples by solid-phase extraction (SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS).
- Vegetables by acetonitrile-based QuEChERS (quick, easy, cheap, effective, rugged and safe) extraction followed by LC-MS/MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Recommended products
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Repr. 2
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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K A Walker et al.
The Biochemical journal, 254(3), 811-817 (1988-09-15)
Concentrations of fluazifop-butyl sprayed on intact plants caused large decreases in the incorporation of radioactivity from [1-14C]acetate into lipids of barley (Hordeum vulgare) leaves and stems, but did not affect leaves or stems of pea (Pisum sativum). Labelling of all
J Hajslová et al.
Journal of chromatography, 438(1), 55-60 (1988-04-01)
Fluazifop-butyl, haloxyfop-ethoxyethyl and quizalofop-ethyl, active ingredients of new selective herbicidal preparations, as well as their metabolites converted in to corresponding methyl esters were separated on several gas chromatographic columns. Bromination of fluazifop esters increased significantly the response of the electron-capture
Ahmed A Tantawy
Journal of the Egyptian Society of Parasitology, 32(3), 837-847 (2003-01-07)
The herbicides, Butachlor and Fluazifop-p-butyl were evaluated against B. alexandrina and their infection with S. mansoni, as well as against the miracidia and cercariae. The tested herbicides reduced the survival and infection rates of B. alexandrina by 28% and 35.71%
Validation and uncertainty study of a comprehensive list of 160 pesticide residues in multi-class vegetables by liquid chromatography-tandem mass spectrometry.
Kmellar B, et al.
Journal of Chromatography A, 1215(1-2), 37-50 (2008)
E Bolygo et al.
Fresenius' journal of analytical chemistry, 368(8), 816-819 (2001-03-03)
An LC-MS-MS assay is described for fluazifop residue analysis in crops. The residues are extracted with acidified organic solvent, the esters and conjugates are hydrolysed with 6 M hydrochloric acid, then the extracts are cleaned-up by solid phase extraction using
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