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686034

Sigma-Aldrich

Lithium aluminum hydride

greener alternative

hydrogen-storage grade

Synonym(s):

LAH, Lithium alanate, Lithium tetrahydroaluminate

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About This Item

Linear Formula:
LiAlH4
CAS Number:
16853-85-3
Molecular Weight:
37.95
EC Number:
240-877-9
MDL number:
MFCD00011075
UNSPSC Code:
26111700
PubChem Substance ID:
329761015
NACRES:
NA.23

grade

hydrogen-storage grade

Assay

>99.95%

form

pellets

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

125 °C (dec.) (lit.)

greener alternative category

, Enabling

SMILES string

[Li].[AlH3]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Lithium aluminum hydride (LAH) is majorly used in hydrogen storage applications. Its properties include high gravimetric and volumetric hydrogen densities. It can also be used as a reducing agent in the preparation of reduced graphene oxide (rGO).

Analysis Note

Hydrogen content, XRD plots and metal purity data are available upon request.

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H260,H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1A - Water-react 1

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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A first-principles study of the electronic structure and stability of a lithium aluminum hydride for hydrogen storage
Song Y, et al.
The Journal of Physical Chemistry B, 110(13), 6906-6910 (2006)
Reversible hydrogen storage via titanium-catalyzed LiAlH4 and Li3AlH6
Chen J, et al.
The Journal of Physical Chemistry B, 105(45), 11214-11220 (2001)
Diastereoselective reductive amination of aryl trifluoromethyl ketones and alpha-amino esters.
Greg Hughes et al.
Angewandte Chemie (International ed. in English), 46(11), 1839-1842 (2007-04-24)
Krishnananda Samanta et al.
Bioorganic & medicinal chemistry letters, 20(1), 283-287 (2009-11-26)
A series of new benzoxazepine derivatives substituted with different alkoxy and aryloxy group were synthesized comprising synthetic steps of Mitsunobu reaction, lithium aluminum hydride (LAH) reduction, followed by debenzylation and finally intramolecular Mitsunobu cyclization. The new benzoxazepines specifically inhibited growth
Damián E Bikiel et al.
Inorganic chemistry, 44(15), 5286-5292 (2005-07-19)
The nature of the solute species present in ethereal solutions of LiAlH(4) is of crucial importance for understanding the mechanisms for the reduction of ketones and other functional groups by LiAlH(4). We have employed a combination of theoretical and experimental
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Articles

Nanoarchitecture of Protective Coatings for Air Sensitive Metal Hydrides

Our research impacts on the hydrogen energy economy through the development of “smart” nanofilms for the protection of metal hydrides against air and moisture, while permitting release of hydrogen gas through these semi permeable nanofilms.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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