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544981

Sigma-Aldrich

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate

99.95% trace metals basis

Synonym(s):

Ru(BPY)3, Ruthenium-tris(2,2′-bipyridyl) dichloride, Tris(2,2′-bipyridyl)ruthenium(II) chloride hexahydrate

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About This Item

Empirical Formula (Hill Notation):
C30H24Cl2N6Ru · 6H2O
CAS Number:
50525-27-4
Molecular Weight:
748.62
MDL number:
MFCD00149670
UNSPSC Code:
12352103
PubChem Substance ID:
24878800
NACRES:
NA.23

Assay

99.95% trace metals basis

mp

>300 °C (lit.)

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2ClH.6H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;;;;;;/h3*1-8H;2*1H;6*1H2;/q;;;;;;;;;;;+2/p-2

InChI key

WHELTKFSBJNBMQ-UHFFFAOYSA-L

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General description

Tris(2,2′-bipyridyl)dichlororuthenium hexahydrate (RTDP, Ru(BPY)3) is an oxygen sensitive fluorescent dye.

Application

RTDP was used to measure the oxygen concentration in a microfluidic chip. A new hybrid material for oxidase based biosensors was prepared by combining Wells–Dawson K7[H4PW18O62]·18H2O (PW18) and RTDP. Silica nanoparticles doped with RTDP render them fluorescent, radio opaque and paramagnetic.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCP1581
MKCM2315
MKCJ7494
MKCG7505
MKCD5321

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Synthesis and Characterization of Fluorescent, Radio-Opaque, and Paramagnetic Silica Nanoparticles for Multimodal Bioimaging Applications
Advanced Materials null
Surface modification of silica nanoparticles to reduce aggregation and nonspecific binding.
Bagwe RP, et al.
Langmuir null
A high-throughput photodynamic therapy screening platform with on-chip control of multiple microenvironmental factors.
Lou X, et al.
Lab on a chip null
Novel organic?inorganic hybrid material based on tris(2,2?-bipyridyl)dichlororuthenium(II) hexahydrate and Dawson-type tungstophosphate K7[H4PW18O62]?18H2O as a bifuctional hydrogen peroxide electrocatalyst for biosensors
Ammam M and Easton EB
Sensors and Actuators B, Chemical, 520-527 null
Surface modification of silica nanoparticles to reduce aggregation and nonspecific binding.
Bagwe RP, et al.
Langmuir, 4357-4362 null
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