07-3750
Diiodomethane
SAJ first grade, ≥98.0%
Synonym(s):
Methylene iodide
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About This Item
Empirical Formula (Hill Notation):
CH2I2
CAS Number:
Molecular Weight:
267.84
Beilstein:
1696892
EC Number:
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
Recommended Products
grade
SAJ first grade
vapor density
9.25 (vs air)
Assay
≥98.0%
form
liquid
availability
available only in Japan
bp
67-69 °C/11 mmHg (lit.)
mp
5-8 °C (lit.)
density
3.325 g/mL at 25 °C (lit.)
SMILES string
ICI
InChI
1S/CH2I2/c2-1-3/h1H2
InChI key
NZZFYRREKKOMAT-UHFFFAOYSA-N
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Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
230.0 °F - closed cup
Flash Point(C)
110 °C - closed cup
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Akimasa Tsujimoto et al.
Journal of dentistry, 38(2), 123-130 (2009-10-14)
This study examined the surface free energy of enamel treated with the single-step self-etching adhesives Bond Force, Clearfil tri-S Bond and G-Bond. The labial enamel surfaces of bovine mandibular incisors were wet ground with #180-grit, #600-grit and #2000-grit silicon carbide
Shaoliang Zhang et al.
Physical chemistry chemical physics : PCCP, 13(24), 11671-11677 (2011-05-20)
Flash photolysis (FP) coupled to resonance fluorescence (RF) was used to measure the absolute rate coefficients (k(1)) for the reaction of OH(X(2)Π) radicals with diiodomethane (CH(2)I(2)) over the temperature range 295-374 K. The experiments involved time-resolved RF detection of the
Jeongho Kim et al.
The journal of physical chemistry. A, 116(11), 2713-2722 (2011-12-01)
We investigate the structural dynamics of iodine elimination reaction of 1,2-diiodoethane (C(2)H(4)I(2)) in cyclohexane by applying time-resolved X-ray liquidography (TRXL). The TRXL technique combines structural sensitivity of X-ray diffraction and 100 ps time resolution of X-ray pulses from synchrotron and
Vasudha Sharma et al.
Journal of combinatorial chemistry, 12(3), 327-331 (2010-03-12)
A mild and efficient protocol for the synthesis of a 2,6-disubstituted pyrimidine-5-carboxylate library via a Morita-Baylis-Hillman (MBH) adduct is described. Herein, the three step methodology involves the use of substituted alpha-iodomethylene beta-keto ester intermediates obtained after oxidation of the MBH
Marie-Christine Lacasse et al.
Journal of the American Chemical Society, 127(36), 12440-12441 (2005-09-08)
A new family of zinc carbenoids derived from phosphoric acids was developed and used in the cyclopropanation of allylic alcohols and ethers and also of unfunctionalized olefins. The use of the chiral phosphoric acid of a 3,3'-disubstituted BINOL leads to
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