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Key Documents

F300

Sigma-Aldrich

Iron(III) acetylacetonate

greener alternative

97%

Synonym(s):

2,4-Pentanedione iron(III) derivative, Fe(acac)3, Ferric acetylacetonate, Iron(III) 2,4-pentanedionate

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About This Item

Linear Formula:
Fe(C5H7O2)3
CAS Number:
Molecular Weight:
353.17
Beilstein:
4157960
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

97%

form

powder

reaction suitability

core: iron
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

180-182 °C (dec.) (lit.)

density

5.24 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

AQBLLJNPHDIAPN-LNTINUHCSA-K

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Non-Precious metal catalyst used by Baran in 2014 to affect the complexity generating reductive coupling of olefins

A Practical and Catalytic Reductive Olefin Coupling
MOCVD precursor for highly crystalline (Zn,Fe)Fe2O4 films and magnetic property measurements of these films.

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Wei Zhang et al.
Journal of environmental sciences (China), 86, 213-224 (2019-12-04)
We investigated the adsorption performance of five Fe-based MOFs (Fe-BTC, MIL-100(Fe), MIL-101(Fe), MIL-53(Fe) and MIL-88C(Fe)) for removal of antimonite (Sb(III)) and antimonate (Sb(V)) from water. Among these MOFs, MIL-101(Fe) exhibited the best adsorption capacities for both Sb(III) and Sb(V) (151.8
Ruth Rodríguez-Ramos et al.
Chemosphere, 236, 124377-124377 (2019-09-25)
In this study, the application of different nanomaterials as dispersants in matrix solid phase dispersion has been evaluated for the extraction of fifteen phthalates from different environmental samples prior to their separation and quantification by ultra-high performance liquid chromatography coupled
Roland Schoch et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 15(17), 3768-3775 (2014-09-13)
A new iron-based catalyst for carbon monoxide oxidation, as a potential substitute for precious-metal systems, has been prepared by using a facile impregnation method with iron tris-acetylacetonate as a precursor on γ-Al2 O3 . Light-off and full conversion temperatures as
Tingting Li et al.
Nanoscale, 7(9), 4171-4178 (2015-02-12)
The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure
Kosuke Suzuki et al.
Dalton transactions (Cambridge, England : 2003), 44(32), 14220-14226 (2015-05-23)
Structurally well-defined hetero-pentanuclear manganese-oxide clusters {MMn4} were successfully synthesized in TBA7Hn[MMn4(OH)2(A-α-SiW9O34)2]·2H2O·C2H4Cl2 (, M = Fe(iii), Co(ii), Ni(ii), Cu(ii), Ga(iii)) by sequential introduction of metal cations into the trivacant lacunary polyoxometalates (POMs). The pentanuclear manganese-oxide cluster {Mn5} showed a small spin

Articles

Metal Organic Frameworks (MOFs)

Professor Randal Lee (University of Houston, USA) discusses design considerations for iron oxide magnetic nanospheres and nanocubes used for biosensing, including synthetic procedures, size, and shape. The effects of these variables are discussed for various volumetric-based and surface-based detection schemes.

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