700665

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

• Synonym(s): (R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate
• Empirical Formula (Hill Notation): C₄₈H₂₉O₄P
• CAS Number: 864943-22-6
• Molecular Weight: 700.72
• MDL number: MFCD12546016
• UNSPSC Code: 12352005
• PubChem Substance ID: 329762222
• NACRES: NA.22

Properties

• form: solid
• optical activity: [α]22/D −44.0°, c = 1 in DMSO
• mp: 390-400 °C
• storage temp.: −20°C
• SMILES string: OP1(=O)Oc2c(cc3ccccc3c2-c4c(O1)c(cc5ccccc45)-c6cc7ccccc7c8ccccc68)-c9cc%10ccccc%10c%11ccccc9%11
• InChI: 1S/C48H29O4P/c49-53(50)51-47-43(41-25-29-13-1-5-17-33(29)37-21-9-11-23-39(37)41)27-31-15-3-7-19-35(31)45(47)46-36-20-8-4-16-32(36)28-44(48(46)52-53)42-26-30-14-2-6-18-34(30)38-22-10-12-24-40(38)42/h1-28H,(H,49,50)
• InChI key: BVICVEIKBNVROI-UHFFFAOYSA-N

Description

Application

Catalyst for:

• Asymmetric hydrogenation cascade
• Enantioselective Friedel-Crafts reaction
• Asymmetric hydrogenation of 2-substituted quinolines
• Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
• Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
• Asymmetric transfer hydrogenation of substituted quinoxalines

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves