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Sigma-Aldrich

16-Phosphonohexadecanoic acid

97%

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About This Item

Empirical Formula (Hill Notation):
C16H33O5P
CAS Number:
443361-18-0
Molecular Weight:
336.40
MDL number:
MFCD09836229
UNSPSC Code:
12352103
PubChem Substance ID:
329761000
NACRES:
NA.23

Assay

97%

form

solid

mp

129-133 °C

SMILES string

OC(=O)CCCCCCCCCCCCCCCP(O)(O)=O

InChI

1S/C16H33O5P/c17-16(18)14-12-10-8-6-4-2-1-3-5-7-9-11-13-15-22(19,20)21/h1-15H2,(H,17,18)(H2,19,20,21)

InChI key

JVXYHUCXFLBBGA-UHFFFAOYSA-N

General description

16-Phosphonohexadecanoic acid (16-PA) is an alkyl phosphonic acid that forms a self-assembled monolayer (SAM). It yields a close packed pattern with densely arranged alkyl groups. These SAMs are robust and stable in aqueous solutions over a wide pH range.

Application

16-PA can be used as an anti-corrosive coating by forming a SAM on metal oxide surfaces for potential use in biomedical applications. It can also be deposited on indium oxide (ITO) substrates for the immobilization of surface atoms.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCC1799
MKBF3983
09630DH

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Assembly of phosphonic acids on GaN and AlGaN
Simpkins BS, et al.
Journal of Physics D: Applied Physics, 43(1), 015303-015303 (2009)
Quantitative photoelectrochemical detection of biotin conjugated CdSe/ZnS quantum dots on the avidin immobilized ITO electrodes
Bas D and ?smail HB
Electroanalysis, 21(16), 1829-1834 (2009)
Self-assembly of organic acid molecules on the metal oxide surface of a cupronickel alloy
Kruszewski KM, et al.
Thin Solid Films, 520(13), 4326-4331 (2012)
Formation of nanosized phosphonic acid self assembled monolayers on cobalt-chromium alloy for potential biomedical applications
Bhure R, et al.
Journal of Biomedical Nanotechnology, 6(2), 117-128 (2010)
Aruna Chandra Singh et al.
Biosensors & bioelectronics, 126, 15-22 (2018-11-06)
Advances in nanostructured materials have facilitated the development of novel sensitive techniques for detection of environmental and clinical analytes. There is immense need for development of devices that can detect analytes at concentrations as low as few pg mL-1. The
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