612162
Phosphoric acid solution
NMR reference standard, 85% in D2O (99.9 atom % D), NMR tube size 4.2 mm × 8 in. , WGS-5BL Coaxial NMR tube
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About This Item
Linear Formula:
H3PO4
CAS Number:
Molecular Weight:
98.00
Beilstein:
1921286
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.12
Recommended Products
grade
NMR reference standard
Quality Level
Assay
83.5-86.5% (gravimetric)
form
solution
concentration
85% in D2O (99.9 atom % D)
technique(s)
NMR: suitable
NMR tube size
4.2 mm × 8 in. , WGS-5BL Coaxial NMR tube
density
1.481 g/cm3
SMILES string
OP(O)(O)=O
InChI
1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)
InChI key
NBIIXXVUZAFLBC-UHFFFAOYSA-N
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General description
Phosphoric acid solution is widely used NMR reference standard.
Application
Phosphoric acid may be employed in the following studies:
- As standard for the determination of phosphorus-31 nuclear magnetic resonance (31P NMR) chemical shifts of the common phospholipids.
- As external standard for the analysis of lipid composition of human white matter by 31P NMR spectroscopy.
- As external standard during the acid-labile phosphorylation of histone H4 by 31P NMR spectroscopy.
- As reference standard to investigate the surface species present on silica/alumina-supported sodium phosphates by pre- and postreaction MAS31P-NMR and FTIR spectroscopies.
Features and Benefits
31P sensitivity
Packaging
Coaxial 4.2 mm O.D. x 8 in. tube (equivalent to Wilmad WGS-5BL) designed to be used inside a 5 mm x 7 in. NMR tube.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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FTIR and 31 P-NMR spectroscopic analyses of surface species in phosphate-catalyzed lactic acid conversion.
Gunter GC, et al.
J. Catal., 164(1), 207-219 (1996)
D S Marinier et al.
Journal of lipid research, 29(9), 1237-1243 (1988-09-01)
In order to study the lipid composition of human white matter, we have developed a 31P NMR spectroscopy method, which allows the determination and quantitation of the main phospholipids found in biological membranes. The technique is based upon the use
P Meneses et al.
Journal of lipid research, 29(5), 679-689 (1988-05-01)
The common phospholipids from biological sources were quantitated using phosphorus-31 nuclear magnetic resonance (NMR) spectroscopy in conjunction with an analytical reagent composed of two parts: 1) 2 ml of reagent chloroform in which was dissolved 0.01-100 mg of crude tissue
J M Fujitaki et al.
Biochemistry, 20(12), 3658-3664 (1981-06-09)
Phosphorus-31 nuclear magnetic resonance (31P NMR) is used to investigate acid-labile phosphorylation of histone H4. 31P NMR detects phosphorylated histidine residues in in vitro enzymatically phosphorylated H4. The source of kinase is nuclei from either regenerating rat liver or Walker-256
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