540765
Poly(p-xylene tetrahydrothiophenium chloride) solution
0.25 wt. % in H2O
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concentration
0.25 wt. % in H2O
refractive index
n20/D 1.3347
pH
1.67
density
1.01 g/mL at 25 °C
fluorescence
λex 322 nm; λem 432 nm in H2O
storage temp.
2-8°C
General description
This intermediate polyelectrolyte can be cast into films of any dimension by evaporation or spin-coating. Thermal curing (250-300°C) under vacuum to drive off the remaining tetrahydrothiophene, HCl, and water yields unsubstituted PPV.
Application
Light-emitting polymer (PPV) precursor.
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Nanoscale research letters, 10, 118-118 (2015-04-09)
Conformation of macromolecules and interchain interactions determine spectral properties of conjugated polymers (CP). An achievement of spatial confinement of isolated chains is one of the routes to use this feature of CP for their purposeful usage. In the present work
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