520160
Shi Epoxidation Diketal Catalyst
98%
Synonym(s):
1,2:4,5-Di-O-isopropylidene-β-D-erythro-2,3-hexodiulo-2,6-pyranose
About This Item
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Quality Level
Assay
98%
optical activity
[α]20/D −120.9°, c = 1 in chloroform
greener alternative product characteristics
Catalysis
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mp
102-104 °C (lit.)
functional group
ether
ketal
ketone
greener alternative category
, Aligned
SMILES string
CC1(C)O[C@@H]2CO[C@]3(COC(C)(C)O3)C(=O)[C@@H]2O1
InChI
1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3/t7-,8-,12+/m1/s1
InChI key
IVWWFWFVSWOTLP-RWYTXXIDSA-N
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General description
Application
An Efficient Catalytic Asymmetric Epoxidation Method
Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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We presents an article regarding asymmetric epoxidation using Shi catalyst.
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