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309338

Sigma-Aldrich

Nickel(II) perchlorate hexahydrate

Synonym(s):

Nickel(2+) diperchlorate hexahydrate

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About This Item

Linear Formula:
Ni(ClO4)2 · 6H2O
CAS Number:
13520-61-1
Molecular Weight:
365.69
EC Number:
237-124-1
MDL number:
MFCD00149804
UNSPSC Code:
12352302
PubChem Substance ID:
24858728
NACRES:
NA.23

form

crystalline

Quality Level

100

reaction suitability

reagent type: oxidant

concentration

15.3-17.0% Ni (EDTA titration)

mp

140 °C (lit.)

application(s)

battery manufacturing

SMILES string

O.O.O.O.O.O.[Ni++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

InChI

1S/2ClHO4.Ni.6H2O/c2*2-1(3,4)5;;;;;;;/h2*(H,2,3,4,5);;6*1H2/q;;+2;;;;;;/p-2

InChI key

WHGYCGOFTBFDLW-UHFFFAOYSA-L

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Application

Starting material for homometallic, trinuclear heteroscorpionate complexes applied in studies of electronic and magnetic properties.

Signal Word

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 3 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Timothy C. Higgs et al.
Inorganic chemistry, 37(9), 2263-2272 (2001-10-24)
The mixed functionality pyrazole/phenol ligand (2-hydroxyphenyl)bis(pyrazolyl)methane, L1OH, has been used to prepare a series of linear trimetallic systems with the general structural motif [M(3)(L1O)(4)](2+), where M = Mn(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+). Each of these complexes has been structurally

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