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261203

Sigma-Aldrich

Samarium

−40 mesh, 99% trace rare earth metals basis

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About This Item

Empirical Formula (Hill Notation):
Sm
CAS Number:
Molecular Weight:
150.36
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.23

Assay

99% trace rare earth metals basis

form

(powder or filings)

reaction suitability

reagent type: catalyst
core: samarium

resistivity

91.4 μΩ-cm, 0°C

particle size

−40 mesh

bp

1794 °C (lit.)

mp

1074 °C (lit.)

density

7.47 g/mL at 25 °C (lit.)

SMILES string

[Sm]

InChI

1S/Sm

InChI key

KZUNJOHGWZRPMI-UHFFFAOYSA-N

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Application

Arylsulfonyl chlorides and arylsulfinates are reduced by a combination of samarium and titanium(IV) chloride to make diaryl disulfides.

Pictograms

Flame

Signal Word

Warning

Hazard Statements

Hazard Classifications

Flam. Sol. 2 - Water-react 3

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Wang, J. Zhang, Y.
Synthetic Communications, 26, 135-135 (1995)
M Majumder et al.
Journal of physics. Condensed matter : an Institute of Physics journal, 25(2), 025701-025701 (2012-12-05)
We report resistivity, magnetization and (19)F NMR results in a polycrystalline sample of SmFeAsO(0.86)F(0.14). The resistivity and magnetization data show a sharp drop at 48 K indicating a superconducting transition. The nuclear spin-lattice rate (1/T(1)) and spin-spin relaxation rate (1/T(2))
Hua Yang et al.
Inorganic chemistry, 52(3), 1275-1284 (2013-01-25)
Sm@C(2v)(3)-C(80) has been separated from the carbon soot produced by electrical arc vaporization of graphite rods doped with Sm(2)O(3) and purified. Its structure has been determined by single crystal X-ray diffraction using cocrystals obtained from either Ni(II)(octaethylporphyrin) (Ni(II)(OEP)) to form
Yi Lu et al.
Optics express, 21(2), 1997-2002 (2013-02-08)
We demonstrate an all-fiber passively Q-switched Yb-doped laser using a piece of Sm-doped fiber as a saturable absorber. The laser was pumped by two 25W, 975 nm fiber coupled diodes and Q-switching was initiated when the ASE generated in the
T Sasikala et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 104, 445-450 (2013-01-01)
Glasses with chemical composition of (62-x) TeO(2)+25 ZnO+8 K(2)O+5 CaO+x Sm(2)O(3) (TZKCSmx; x=0.1, 0.5, 1.0, 1.5 mol%) were prepared by melt quenching technique. The absorption spectrum was recorded in the UV-visible and NIR regions. The oscillator strengths of absorption bands

Articles

The unique properties of the rare-earth elements and their alloys have brought them from relative obscurity to high profile use in common hightech applications.

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