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230847

Sigma-Aldrich

5-Methyl-1,10-phenanthroline

≥99%

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About This Item

Empirical Formula (Hill Notation):
C13H10N2
CAS Number:
3002-78-6
Molecular Weight:
194.23
EC Number:
221-099-9
MDL number:
MFCD00004982
UNSPSC Code:
12352100
PubChem Substance ID:
24853839
NACRES:
NA.22

Assay

≥99%

form

powder

mp

113-114 °C (lit.)

solubility

methanol: soluble 50 mg/mL, clear to slightly hazy, colorless to yellow

SMILES string

Cc1cc2cccnc2c3ncccc13

InChI

1S/C13H10N2/c1-9-8-10-4-2-6-14-12(10)13-11(9)5-3-7-15-13/h2-8H,1H3

InChI key

UJAQYOZROIFQHO-UHFFFAOYSA-N

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General description

5-Methyl-1,10-phenanthroline forms iron(II)-phenanthroline complexes and their gas-phase stabilities has been investigated in an electrospray ionization mass spectrometer.

Application

5-Methyl-1,10-phenanthroline was used in the determination of Cu(II) in duralmin alloy by capillary zone electrophoresis.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Zdeněk Trávníček et al.
Chemistry Central journal, 6(1), 160-160 (2012-12-22)
Inspired by the unprecedented historical success of cisplatin, one of the most important research directions in bioinorganic and medicinal chemistry is dedicated to the development of new anticancer compounds with the potential to surpass it in antitumor activity, while having
Capillary electrophoretic separation of several transition-metal ions as their complexes with 1, 10-phenanthroline derivatives and its application to the determination of copper in duralmin alloys.
Yokoyama T, et al.
Analytica Chimica Acta, 364(1), 75-81 (1998)
Sandor Keki et al.
Journal of the American Society for Mass Spectrometry, 17(7), 962-966 (2006-05-23)
The gas-phase stabilities of Fe(Phi)3(2+) complexes, where Phi represents the 1,10-phenanthroline, 5-chloro-1,10-phenanthroline, 5-methyl-1,10-phenanthroline, 3,4,7,8-tetramethyl-1,10-phenanthroline, and 4,7-diphenyl-1,10-phenanthroline ligands were investigated by collision-induced dissociation (CID) in the capillary-first skimmer region upon changing the voltage difference between the capillary and the skimmer. The
Tiffany K Rundstadler et al.
Molecules (Basel, Switzerland), 23(9) (2018-09-06)
Cancer stem cells (CSCs) are thought of as a clinically pertinent subpopulation of tumors, partly responsible for cancer relapse and metastasis. Research programs aimed at discovering anti-CSC agents have largely focused on biologics and purely organic molecules. Recently, we showed
K Benjamin Garbutcheon-Singh et al.
Dalton transactions (Cambridge, England : 2003), 42(4), 918-926 (2012-09-29)
Twelve metallointercalators of the type [Pt(I(L))(A(L))](2+), where A(L) is either the R,R or S,S enantiomer of 1,2-diaminocyclopentane (DACP) and I(L) is either 1,10-phenathroline, 4-methyl-1,10-phenanthroline, 5-methyl-1,10-phenanthroline, 4,7-dimethyl-1,10-phenanthroline, 5,6-dimethyl-1,10-phenanthroline or 3,4,7,8-tetramethyl-1,10-phenanthroline, were synthesised, characterised and the cytotoxicity to the L1210 cell line
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