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216186

Sigma-Aldrich

Potassium selenocyanate

reagent grade, 97%

Synonym(s):

Selenocyanic acid potassium

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About This Item

Linear Formula:
KSeCN
CAS Number:
3425-46-5
Molecular Weight:
144.08
Beilstein:
3912121
EC Number:
222-320-1
MDL number:
MFCD00011366
UNSPSC Code:
12352302
PubChem Substance ID:
24852939
NACRES:
NA.23

grade

reagent grade

Assay

97%

form

solid

technique(s)

NMR: suitable

mp

100 °C

SMILES string

[K][Se]C#N

InChI

1S/CHNSe.K/c2-1-3;/h3H;/q;+1/p-1

InChI key

KYEKHFSRAXRJBR-UHFFFAOYSA-M

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General description

Potassium selenocyanate is a crystalline solid and a reagent for the conversion of alkyl halides to nitriles, and the production of pharmaceutical intermediates. It also finds application in the field of energy storage devices.

Application

Potassium selenocyanate can be used as a:
  • Redox-active electrolyte to enhance the performance of carbon-based supercapacitors.
  • Starting material for the one-pot stereoselective synthesis of alkyl styryl selenides.
  • Precursor to synthesize Cu and Ni complexes with antioxidant/anti-inflammatory activities.
  • Selenylating agent to prepare stereoselective selenoglycosides and selenium-linked disaccharides.

Signal Word

Danger

Hazard Statements

H300,H331,H373,H410

Hazard Classifications

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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J. Ind. Chem. Soc., 62, 800-800 (1985)
Eric Block et al.
Journal of the American Chemical Society, 128(46), 14949-14961 (2006-11-16)
More than 40 new 4- to 12-membered ring heterocycles containing various combinations of Group 14 and 16 elements Si, Sn, S, Se, and Te have been synthesized and fully characterized. Synthesis of these small-ring as well as medium-ring (mesocyclic) heterocycles
Journal of the Chemical Society. Chemical Communications, 860-860 (1991)
Tetrahedron, 46, 7735-7735 (1990)
Rajmund Mokso et al.
Physical chemistry chemical physics : PCCP, 10(28), 4138-4146 (2008-07-10)
The microwave spectra of propa-1,2-dienyl selenocyanate, H(2)C==C==CHSeC[triple bond]N, and cyclopropyl selenocyanate, C(3)H(5)SeC[triple bond]N, are reported. The spectra of the ground and two vibrationally excited states of the (80)Se isotopologue and the spectrum of the ground state of the (78)Se isotopologue
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