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06203

Sigma-Aldrich

Sodium hydroxide

puriss., meets analytical specification of Ph. Eur., BP, NF, E524, 98-100.5%, pellets

Synonym(s):

‘Caustic soda’

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About This Item

Linear Formula:
NaOH
CAS Number:
1310-73-2
Molecular Weight:
40.00
EC Number:
215-185-5
MDL number:
MFCD00003548
UNSPSC Code:
12352302
PubChem Substance ID:
329748217
NACRES:
NA.21

vapor density

>1 (vs air)

Quality Level

200

vapor pressure

<18 mmHg ( 20 °C)
3 mmHg ( 37 °C)

grade

puriss.

Assay

98-100.5%

form

pellets

quality

meets analytical specification of Ph. Eur., BP, NF, E524

impurities

≤0.0005% total nitrogen (N)
≤0.002% heavy metals (as Pb)
≤0.5% Na2CO3

mp

318 °C (lit.)

solubility

water: soluble 1260 g/L at 20 °C

density

2.13 g/cm3 at 20 °C

anion traces

chloride (Cl-): ≤20 mg/kg
phosphate (PO43-): ≤10 mg/kg
silicate (as SiO2): ≤100 mg/kg
sulfate (SO42-): ≤30 mg/kg

cation traces

Al: ≤10 mg/kg
As: ≤2 mg/kg
Ca: ≤10 mg/kg
Fe: ≤10 mg/kg
Hg: ≤1 mg/kg
K: ≤1000 mg/kg
Pb: ≤0.5 mg/kg

SMILES string

[OH-].[Na+]

InChI

1S/Na.H2O/h;1H2/q+1;/p-1

InChI key

HEMHJVSKTPXQMS-UHFFFAOYSA-M

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General description

Sodium hydroxide, also known as lye and caustic soda, is a strong base used universally as a neutralization agent in the chemical industry, paper making, petroleum refining, cleaning compounds, and drain cleaners.

Application

Sodium hydroxide can be used as:
  • A reagent in the gold-catalyzed selective oxidation of glycerol to glyceric acid.
  • A catalyst for the cross-dehydrogenative coupling of alcohols and hydrosilanes to synthesize silyl ethers.
  • A base in the transition-metal free Sonogashira-type couplings of aryl halides and alkynes to synthesize ynones in the presence of PEG as a phase-transfer agent.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H290 - H314

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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M A Roberts et al.
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Chemoselective, solvent-free aldol condensation reaction.
Raston CL and Scott JL.
Green Chemistry, 2(2), 49-52 (2000)
M Chevallet et al.
Electrophoresis, 19(11), 1901-1909 (1998-09-18)
Severe quantitative loss of protein is often observed in high-resolution two-dimensional electrophoresis of membrane proteins, while the resolution is usually not affected. To improve the solubility of proteins in this technique, we tested denaturing cocktails containing various detergents and chaotropes.
Kinetics of sodium borohydride direct oxidation and oxygen reduction in sodium hydroxide electrolyte: Part I. BH4- electro-oxidation on Au and Ag catalysts.
Chatenet M, et al.
Electrochimica Acta, 51(25), 5459-5467 (2006)
Silvio Carrettin et al.
Chemical communications (Cambridge, England), (7)(7), 696-697 (2002-07-18)
Glycerol is oxidised to glyceric acid with 100% selectivity using either 1% Au/charcoal or 1% Au/graphite catalyst under mild reaction conditions (60 degrees C, 3 h, water as solvent).
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