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Supelco

Fenoxaprop-ethyl

PESTANAL®, analytical standard

Synonym(s):

Ethyl 2-{4-[(6-chlorobenzoxazol-2-yl)oxy]phenoxy}propionate

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About This Item

Empirical Formula (Hill Notation):
C18H16ClNO5
CAS Number:
Molecular Weight:
361.78
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

quality

racemate

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

CCOC(=O)C(C)Oc1ccc(Oc2nc3ccc(Cl)cc3o2)cc1

InChI

1S/C18H16ClNO5/c1-3-22-17(21)11(2)23-13-5-7-14(8-6-13)24-18-20-15-9-4-12(19)10-16(15)25-18/h4-11H,3H2,1-2H3

InChI key

PQKBPHSEKWERTG-UHFFFAOYSA-N

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General description

Fenoxaprop-ethyl is a postemergence herbicide used for the control of annual and perennial weeds in crops. Its mode of action involves inhibiting the fatty acid biosynthesis in plant meristems, which in turn affects the activity of acetyl-coenzyme A carboxylase.

Application

Fenoxaprop-ethyl may be used as a reference standard for the determination of fenoxaprop-ethyl by high performance liquid chromatography (HPLC) with photometric detection and mass spectrometry.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Biodegradation of fenoxaprop-ethyl by an enriched consortium and its proposed metabolic pathway.
Dong W, et al.
International Biodeterioration & Biodegradation, 97, 159-167 (2015)
Determination of fenoxaprop-ethyl in agricultural products by HPLC with photometric detection and mass spectrometry.
Ishimitsu S, et al.
Journal of Health Science, 49(6), 492-496 (2003)
Yanfeng Zhang et al.
Journal of agricultural and food chemistry, 58(24), 12878-12884 (2010-12-03)
The enantioselective degradation behavior of fenoxaprop-ethyl (FE) and its chiral metabolite fenoxaprop (FA) in three soils under native conditions was investigated. Two pairs of enantiomers were analyzed by high-performance liquid chromatography (HPLC) with an amylose tri-(3,5-dimethylphenylcarbamate) (ADMPC) chiral column. The
Jing Lin et al.
Journal of agricultural and food chemistry, 55(18), 7626-7629 (2007-08-10)
Hydrolysis of fenoxaprop-p-ethyl (FE), a widely used herbicide, was studied in aqueous buffer solutions at pH ranging from 4.0 to 10.0. The degradation kinetics, strongly dependent on pH values, followed first-order kinetics. FE was relatively stable in neutral media, whereas
Ying Hou et al.
FEMS microbiology letters, 323(2), 196-203 (2011-11-19)
An enrichment culture which completely degraded fenoxaprop-ethyl (FE) was acquired by using FE as sole carbon source. An efficient FE-degrading strain T1 was isolated from the enrichment culture and identified as Rhodococcus sp. Strain T1 could degrade 94% of 100

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