904694
Ir(p-CF3-ppy)3
≥95%
Synonym(s):
Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium
Sign Into View Organizational & Contract Pricing
All Photos(3)
About This Item
Empirical Formula (Hill Notation):
C36H21F9IrN3
CAS Number:
Molecular Weight:
858.77
UNSPSC Code:
12161600
NACRES:
NA.22
Recommended Products
![Tris[2-(p-tolyl)pyridine]iridium(III) ≥99% (HPLC)](/deepweb/assets/sigmaaldrich/product/structures/207/957/bb807380-3690-46c2-809e-e6bc2ba29fa5/640/bb807380-3690-46c2-809e-e6bc2ba29fa5.png)
![1-Chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) >95% in F+ active](/deepweb/assets/sigmaaldrich/product/structures/206/487/53d52ee5-ef71-4e9a-9bc8-938b68b98d5d/640/53d52ee5-ef71-4e9a-9bc8-938b68b98d5d.png)
Assay
≥95%
form
powder or crystals
reaction suitability
core: iridium
reagent type: catalyst
reaction type: Photocatalysis
mp
>300 °C
photocatalyst activation
465 nm
Application
This photocatalyst facilitates a variety of transformations using visible light, including the defluorination of arenes.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
A Singh et al.
Chemical science, 6(12), 7206-7212 (2015-12-01)
C-F functionalizations that provide C-C bonds are challenging synthetic transformations, due in part to the large C-F bond strength, short bond length, nonpolarizable nature, the production of fluoride, and the regioselectivity-in the case of multifluorinated substrates. However, commercially available highly
Facile synthesis and complete characterization of homoleptic and heteroleptic cyclometalated Iridium(III) complexes for photocatalysis
Singh A, et al.
Journal of Organometallic Chemistry, 776, 51-59 (2015)
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service