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809063

Sigma-Aldrich

Sodium 1-Phenoxy-methanesulfinate

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About This Item

Empirical Formula (Hill Notation):
C7H7NaO3S
Molecular Weight:
194.18
UNSPSC Code:
12352200
PubChem Substance ID:
NACRES:
NA.22

form

powder or crystals

Quality Level

reaction suitability

reaction type: C-C Bond Formation
reaction type: C-H Activation
reagent type: catalyst

SMILES string

O=S(O[Na])COC1=CC=CC=C1

InChI

1S/C7H8O3S.Na/c8-11(9)6-10-7-4-2-1-3-5-7;/h1-5H,6H2,(H,8,9);/q;+1/p-1

InChI key

KITYKPJDXMLWTO-UHFFFAOYSA-M

General description

Sodium 1-Phenoxy-methanesulfinate is a sulfinate reagent bearing a phenoxy moiety.

Application

The following Baran Sulfinate is a part of a toolbox of diversification reagents which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Legal Information

Diversinates is a trademark of Sigma-Aldrich Co. LLC

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Articles

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. The ever-growing demand for new chemical entities, coupled with dwindling resources and time constraints allotted to any given research project, a rapid way to diversify (hetero)aromatic scaffolds is needed.

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