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73261

Sigma-Aldrich

1-Butyl-4-methylpyridinium tetrafluoroborate

≥97.0% (T)

Synonym(s):

1-Butyl-4-picolinium tetrafluoroborate, 4MBPBF4

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About This Item

Empirical Formula (Hill Notation):
C10H16BF4N
CAS Number:
343952-33-0
Molecular Weight:
237.05
Beilstein:
9019838
MDL number:
MFCD03095460
UNSPSC Code:
12352100
PubChem Substance ID:
57652469
NACRES:
NA.22

Assay

≥97.0% (T)

form

liquid

refractive index

n20/D 1.4

density

1.20 g/mL at 20 °C (lit.)

SMILES string

F[B-](F)(F)F.CCCC[n+]1ccc(C)cc1

InChI

1S/C10H16N.BF4/c1-3-4-7-11-8-5-10(2)6-9-11;2-1(3,4)5/h5-6,8-9H,3-4,7H2,1-2H3;/q+1;-1

InChI key

VISYYHYJMCAKAF-UHFFFAOYSA-N

Related Categories

General description

Pyridinium based ionic liquid

Application

4MBPBF4 has been used in the preparation of the SWNT-polymer composite films to improve the dispersion of SWNTs and conductivity of the composites (SWNT= singlewalled carbon nanotubes). The use of 4MBPBF4 as a reaction media during derivatization of dimethyl sulfate with dibenzazepine, accelerates the rate of the reaction. It can also be used to modify carbon paste electrode, which leads to high sensitivity, selectivity and low detection limit for both potassium ferricyanide and dopamine by cyclic voltammetric technique.

Other Notes

Lipase catalyzed kinetic resolution in ionic liquids with improved enantioselectivity

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCBR0677V
1441367V
1441367
1305123
1102629

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Sigma-Aldrich

04365

1-Ethyl-3-methylimidazolium tetrafluoroborate

Mixing thermodynamic properties of 1-butyl-4-methylpyridinium tetrafluoroborate [b4mpy][BF 4] with water and with an alkan-1ol (methanol to pentanol)
Ortega, J., et al.
The Journal of Chemical Thermodynamics, 40.7, 1087-1094 (2008)
Electrochemical investigations of potassium ferricyanide and dopamine by 1-butyl-4-methylpyridinium tetrafluoro borate modified carbon paste electrode: A cyclic voltammetric study.
Pandurangachar M, et al.
International Journal of Electrochemical Science, 5(8), 1187-1202 (2010)
Transparent Stretchable Single-Walled Carbon Nanotube-Polymer Composite Films with Near-Infrared Fluorescence.
Ma R, et al.
Advanced Materials, 25(18), 2548-2553 (2013)
S. Schofer et al.
Chemical Communications (Cambridge, England), 425-425 (2001)
Mixed ionic liquid as electrolyte for lithium batteries
Diaw, M., et al.
Journal of Power Sources, 146.1, 682-684 (2005)
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Protocols

Enzymatic Reactions in Ionic Liquids

One of the most popular lipase for synthetic use is the Candida antarctica lipase (CALB). CALB catalyzes the enantioselective acylation of 1-phenylethylamine with 4-pentenoic acid

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