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705551

Sigma-Aldrich

Hydrogen chloride solution

3 M in cyclopentyl methyl ether (CPME)

Synonym(s):

Hydrochloric acid in CPME

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About This Item

Empirical Formula (Hill Notation):
HCl
CAS Number:
7647-01-0
Molecular Weight:
36.46
MDL number:
MFCD00011324
UNSPSC Code:
12352301
PubChem Substance ID:
329762569
NACRES:
NA.22

form

liquid

Quality Level

100

concentration

2.85-3.30 M (silver nitrate titration)
3 M in cyclopentyl methyl ether (CPME)

bp

106 °C

density

0.895 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Cl

InChI

1S/ClH/h1H

InChI key

VEXZGXHMUGYJMC-UHFFFAOYSA-N

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Application

Hydrogen chloride solution can be used in the Pinner synthesis of imidate hydrochlorides, which involves acid-catalyzed condensation of a nitrile and an alcohol under anhydrous conditions.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

50.0 °F

Flash Point(C)

10 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBN8669
SHBM2078
SHBL6343
SHBL5283
SHBK9085

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The Chemistry of Imidates.
Roger R and Neilson D G
Chemical Reviews, 61(2), 179-211 (1961)
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