520853
Potassium tetrachloroplatinate(II)
≥99.9% trace metals basis
Synonym(s):
Potassium platinum(II) chloride
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About This Item
Linear Formula:
K2PtCl4
CAS Number:
Molecular Weight:
415.09
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
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Assay
≥99.9% trace metals basis
form
powder or crystals
composition
Pt, ≥46.2%
impurities
≤1000.0 ppm Trace Metal Analysis
density
3.38 g/mL at 25 °C (lit.)
SMILES string
[K+].[K+].Cl[Pt--](Cl)(Cl)Cl
InChI
1S/4ClH.2K.Pt/h4*1H;;;/q;;;;2*+1;+2/p-4
InChI key
RVRDLMCWUILSAH-UHFFFAOYSA-J
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General description
Potassium tetrachloroplatinate(II) is a crystalline solid that is insoluble in water and soluble in organic solvents. It is widely used in the field of nanomaterial synthesis, catalysis, and energy storage.
Application
Potassium tetrachloroplatinate(II) can be used:
- As a precursor to prepare platinum nanoparticles and mesoporous platinum nanospheres with tunable pore sizes.
- As a catalyst for selective methane oxidation through C-H activation. In addition, to synthesize octahedral Pd@Pt1.8Ni nanocrystals with an ultrathin PtNi alloy shell. The nanocrystals exhibited better ORR activity and durability than the commercial Pt/C for fuel cells.
- To prepare Pt atomic clusters were synthesized using a one-step carbon-defect-driven electroless deposition method. These catalysts demonstrated low overpotential, high activity for the hydrogen evolution reaction, exceptional stability, and improved utilization efficiency of Pt. The Pt-AC/DG (Atomic Clusters/Defective Graphene) cathode showed excellent hydrogen production activity, remarkable stability, and significantly reduced Pt usage compared to the Pt/C catalyst.
- As a starting material to synthesize cyclometalated platinum(II) complexes with long-lived luminescence in solution.
Features and Benefits
Reacts with bis(dithiolates) to form metal-bis(dithiolates) with applications in laser Q-switch materials, liquid crystals, optical CD recording media, bar code materials and superconductivity. Reacts with capping polymers to form shape-control colloidal platinum nanoparticles for catalysis and photocatalysts.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Z T Lalowicz et al.
Solid state nuclear magnetic resonance, 8(2), 89-107 (1997-04-01)
Expressions are derived for the initial relaxation rate 1/T1 of protons and deuterons of nontunnelling NH4 and ND4 groups reorienting about various symmetry axes in solids. The reorientation rates are modified by a trigonal, tetragonal or monoclinic distortion of the
Erik Ullerås et al.
Toxicology, 206(2), 245-256 (2004-12-14)
Predictive testing of immunotoxicity associated with chemical compounds is complicated and cannot be accomplished with a single test. As most of the existing tests for immunotoxicity employ experimental animals, there is an increasing need for alternative tests in vitro. We
T Kusumoto et al.
International journal of hyperthermia : the official journal of European Society for Hyperthermic Oncology, North American Hyperthermia Group, 11(4), 575-586 (1995-07-01)
To investigate the greatest therapeutic efficacy, we investigated the effect of scheduling on the cytotoxic interaction between hyperthermia and seven different platinum complexes in vitro and in vivo using the FSaII murine fibrosarcoma cells. Hyperthermia treatment (43 degrees C, 1
P Koch et al.
Contact dermatitis, 34(4), 253-257 (1996-04-01)
We report a patient with contact stomatitis due to combined sensitization to palladium and platinum. Patch testing showed strong and persistent allergic patch test reactions to palladium chloride (1% pet.), ammonium tetrachloroplatinate (0.25% pet.), and a palladium metal plate. A
Gordana N Ostojic et al.
Langmuir : the ACS journal of surfaces and colloids, 24(17), 9784-9789 (2008-07-24)
A method for noncovalent functionalization of DNA-wrapped single-walled carbon nanotubes (SWNTs) using platinum-based DNA cross-linkers is investigated. In particular, cisplatin and potassium tetrachloroplatinate are shown to bind to DNA that encapsulates SWNTs in aqueous solution. The bound platinum salt can
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