515477
4,4′-Di-tert-butyl-2,2′-dipyridyl
98%
Synonym(s):
4,4′-Bis(tert-butyl)-2,2′-bipyridine, BBBPY
About This Item
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Assay
98%
mp
159-161 °C (lit.)
SMILES string
CC(C)(C)c1ccnc(c1)-c2cc(ccn2)C(C)(C)C
InChI
1S/C18H24N2/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6/h7-12H,1-6H3
InChI key
TXNLQUKVUJITMX-UHFFFAOYSA-N
Application
- In the synthesis of oxidovanadium(IV) complex [VOCl2(dbbpy)(H2O)], which is used as a catalyst for the epoxidation of cyclooctene in the presence of tert-butyl hydroperoxide.
- In iron-catalyzed ortho-allylation of 1-arylpyrazoles via C-H activation.
- In iridium-catalyzed borylation of (hetero)arenes.
- In iron-catalyzed arylation of heterocycles in the presence of metallic Mg.
- In nickel-catalyzed decarboxylation of block copolymers.
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral
Storage Class Code
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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