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About This Item
Linear Formula:
(CH3S)2CS
CAS Number:
Molecular Weight:
138.27
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
98%
form
liquid
refractive index
n20/D 1.675 (lit.)
bp
101-102 °C/12 mmHg (lit.)
mp
−3 °C (lit.)
density
1.254 g/mL at 25 °C (lit.)
SMILES string
CSC(=S)SC
InChI
1S/C3H6S3/c1-5-3(4)6-2/h1-2H3
InChI key
IQWMXKTYXNMSLC-UHFFFAOYSA-N
Related Categories
Application
Dimethyl trithiocarbonate may be used in the following studies:
- Preparation of methyl-β,β′-dicarbonyldithiocarboxylate derivatives.
- Generation of tris(organothiyl)methyl radicals and these radicals were evaluated using EPR spectroscopy.
- Preparation of β-oxodithiocarboxylates.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
206.6 °F - closed cup
Flash Point(C)
97 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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A New Application of Dimethyl Trithiocarbonate. Methylthiothiocarbonylation of 2, 4-Pentanedione and Some β-Oxoesters.
Oliva A, et al.
Synthetic Communications, 28(18), 3381-3386 (1998)
Gas-Phase Thermolysis, 14. On the Isomerization of Dimethyl Carbonate and Its Mono-, Di-, and Trithio Analogs.
Egsgaard H, et al.
Chemische Berichte, 124(5), 1265-1270 (1999)
A facile method for the synthesis of substituted 2-ylidene-1, 3-oxathioles from acetophenones.
Samuel R, et al.
Tetrahedron Letters, 48(47), 8376-8378 (2007)
An electron paramagnetic resonance study of free-radical additions to trithiocarbonates and of the formation and destruction of tetrathiafulvalene by free-radical processes.
Forrest D and Ingold KU.
Journal of the American Chemical Society, 100(12), 3868-3873 (1978)
Dirk Stueber et al.
Solid state nuclear magnetic resonance, 22(4), 439-457 (2003-01-24)
The 13C chemical shift tensor principal values for the trigonal carbonate and thiocarbonate carbon atoms in the dialkyl carbonates, dimethyl carbonate, ethylene carbonate, and diphenyl carbonate, and in the trithiocarbonates, ethylene trithiocarbonate and dimethyl trithiocarbonate, respectively, were measured in various
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