394262

Octadecylmagnesium chloride solution

0.5 M in THF

• Synonym(s): Chlorooctadecylmagnesium, Octadecane, magnesium complex
• Linear Formula: CH₃(CH₂)₁₇MgCl
• CAS Number: 116980-66-6
• Molecular Weight: 313.24
• MDL number: MFCD00012233
• UNSPSC Code: 12352103
• PubChem Substance ID: 24864583
• NACRES: NA.22

Properties

• Quality Level: 100
• reaction suitability: reaction type: Grignard Reaction
• concentration: 0.5 M in THF
• bp: 67 °C
• density: 0.906 g/mL at 25 °C
• SMILES string: CCCCCCCCCCCCCCCCCC[Mg]Cl
• InChI: 1S/C18H37.ClH.Mg/c1-3-5-7-9-11-13-15-17-18-16-14-12-10-8-6-4-2;;/h1,3-18H2,2H3;1H;/q;;+1/p-1
• InChI key: ONJPXWZQVLKGIU-UHFFFAOYSA-M

Description

General description

Octadecylmagnesium chloride is a Grignard reagent commonly used in organic synthesis for various transformations, including nucleophilic addition reactions and carbon-carbon bond formation via palladium-catalyzed alkylation and arylation reactions.

Application

Octadecylmagnesium chloride can be used for the introduction of octyl substituents on the bipyridine skeletons to prepare functionalized 4,4′-bipyridines, which are used as linkers formation of discrete metal complexes.

Safety Information

• Pictograms: GHS02,GHS05,GHS07,GHS08
• Signal Word: Danger
• Hazard Statements: H225 - H302 - H314 - H335 - H351
• Precautionary Statements: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Hazard Classifications: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Supplementary Hazards: EUH014 - EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 1
• Flash Point(F): -4.0 °F - closed cup
• Flash Point(C): -20 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves