339121
Zirconium(IV) ethoxide
97%
Synonym(s):
Tetraethoxyzirconium, Zirconium ethoxide (Zr(OEt)4 ), Zirconium tetraethoxide
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About This Item
Linear Formula:
Zr(OC2H5)4
CAS Number:
Molecular Weight:
271.47
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
Quality Level
Assay
97%
form
solid
reaction suitability
core: zirconium
reagent type: catalyst
bp
235 °C/5 mmHg (lit.)
SMILES string
CCO[Zr](OCC)(OCC)OCC
InChI
1S/4C2H5O.Zr/c4*1-2-3;/h4*2H2,1H3;/q4*-1;+4
InChI key
ASBGGHMVAMBCOR-UHFFFAOYSA-N
Application
Convenient precursor for the synthesis of olefin-functionalized zirconium-containing monomers, which have potential for the generation of hybrid zirconium-containing polymers.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
4.1B - Flammable solid hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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William J. Evans et al.
Inorganic chemistry, 38(6), 1160-1164 (2001-10-24)
The attachment of pendent olefin groups to oxygen-ligated zirconium complexes using olefin-substituted phenols and alcohols and readily accessible zirconium reagents is described. Syntheses of three crystallographically characterizable complexes isolable in 55-90% yield are reported. Eugenol, HOC(6)H(3)(OMe-2)(CH(2)CH=CH(2)-4) (HOAr) reacts with [Zr(O(i)Pr)(4)(HO(i)Pr)](2)
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