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324175

Sigma-Aldrich

Lithium 2-thienylcyanocuprate solution

0.25 M in THF

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About This Item

Empirical Formula (Hill Notation):
C5H3CuLiNS
CAS Number:
112426-02-5
Molecular Weight:
179.64
MDL number:
MFCD00013443
UNSPSC Code:
12352103
PubChem Substance ID:
24859429
NACRES:
NA.22

form

liquid

concentration

0.25 M in THF

density

0.895 g/mL at 25 °C

SMILES string

[Li]N=C=[Cu]c1cccs1

InChI

1S/C4H3S.CN.Cu.Li/c1-2-4-5-3-1;1-2;;/h1-3H;;;/q;-1;;+1

InChI key

BDZYNOMLDVYLHW-UHFFFAOYSA-N

General description

Learn More at the Professor and Product Portal of Professor Bruce Lipshutz.

Application

Useful reagent for the preparation of higher-order cuprates.

Signal Word

Danger

Hazard Statements

H225,H302,H319,H335,H351

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL4605
SHBH2381V
SHBB5998
62296DJ
14615HH

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Aldrichimica Acta, 20, 58-58 (1987)

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