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283738

Sigma-Aldrich

Potassium aquapentachlororuthenate(III)

Synonym(s):

Dipotassium aquapentachlororuthenate(III)

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About This Item

Linear Formula:
K2RuCl5(H2O)
CAS Number:
14404-33-2
Molecular Weight:
374.55
EC Number:
238-374-4
MDL number:
MFCD00011524
UNSPSC Code:
12352302
PubChem Substance ID:
24857128
NACRES:
NA.23

form

powder

Quality Level

200

concentration

26-30% Ru (gravimetric)

technique(s)

H-NMR: suitable

SMILES string

O.[K+].[K+].Cl[Ru--](Cl)(Cl)(Cl)Cl

InChI

1S/5ClH.2K.H2O.Ru/h5*1H;;;1H2;/q;;;;;2*+1;;+3/p-5

InChI key

SRVGBBZEPHUDFZ-UHFFFAOYSA-I

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Application

The product may be used for eletrodeposition of bifunctional catalyst films, PtRu on nanoporous TiO2 substrates.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315 - H319 - H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Nanoporous TiO 2-supported bimetallic catalysts for methanol oxidation in acidic media.
Hepel M, et al.
Electrochemical Communications, 8(9), 1439-1444 (2006)
Sunder N Dhuri et al.
Dalton transactions (Cambridge, England : 2003), 44(16), 7634-7642 (2015-03-27)
A mononuclear high-valent trans-dioxoruthenium(VI) complex, trans-[Ru(VI)(TMC)(O)2](2+) (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), was synthesized and characterized by various spectroscopic techniques and X-ray crystallography. The reactivity of the trans-[Ru(VI)(TMC)(O)2](2+) complex was investigated in hydride transfer and hydrogen atom transfer reactions. The mechanism of hydride

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