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243965

Sigma-Aldrich

Phenylselenyl bromide

98%

Synonym(s):

Benzeneselenenyl bromide, Benzeneselenyl bromide

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About This Item

Linear Formula:
C6H5SeBr
CAS Number:
34837-55-3
Molecular Weight:
235.97
Beilstein:
2039772
EC Number:
252-238-1
MDL number:
MFCD00000047
UNSPSC Code:
12352100
PubChem Substance ID:
24854643
NACRES:
NA.22

Quality Level

100

Assay

98%

form

solid

bp

107-108 °C/15 mmHg (lit.)

mp

58-62 °C (lit.)

SMILES string

Br[Se]c1ccccc1

InChI

1S/C6H5BrSe/c7-8-6-4-2-1-3-5-6/h1-5H

InChI key

LCEFEIBEOBPPSJ-UHFFFAOYSA-N

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Application

Phenylselenyl bromide was used in the preparation of exo-2-methyl-7-phenylselenyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione and endo-2-methyl-7-phenylselanyl-octahydro-8-oxa-2,7b-diaza-dicyclopenta[a,e]pentalene-1,3-dione. It was also used in the synthesis of enones by selenenylation of α-cyano ketones with lithium naphthalenide.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Met. Corr. 1 - STOT RE 2

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synlett, 1274-1274 (2007)
X= Y?ZH Systems as potential 1, 3-dipoles. Part 52: Fused-ring forming electrophile induced oxime→nitrone→ cycloaddition cascades.
Ali Dondas H, et al.
Tetrahedron Letters, 57(32), 7035-7045 (2001)
Santanu Hati et al.
European journal of medicinal chemistry, 100, 188-196 (2015-06-19)
Herein we have reported design, synthesis and in vitro biological evaluation of a library of bicyclic lactams that led to the discovery of compounds 6 and 7 as a novel class of α-glucosidase inhibitors. They inhibited α-glucosidase (yeast origin) in a

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