157317

Cyclopropyltriphenylphosphonium bromide

98%

• Synonym(s): NSC 110599
• Linear Formula: C₃H₅P(C₆H₅)₃Br
• CAS Number: 14114-05-7
• Molecular Weight: 383.26
• Beilstein: 4170278
• EC Number: 237-970-1
• MDL number: MFCD00011872
• UNSPSC Code: 12352002
• PubChem Substance ID: 24849670
• NACRES: NA.22

Properties

• Assay: 98%
• form: solid
• reaction suitability: reaction type: C-C Bond Formation
• mp: 178-181 °C (lit.)
• functional group: phosphine
• SMILES string: [Br-].C1CC1[P+](c2ccccc2)(c3ccccc3)c4ccccc4
• InChI: 1S/C21H20P.BrH/c1-4-10-18(11-5-1)22(21-16-17-21,19-12-6-2-7-13-19)20-14-8-3-9-15-20;/h1-15,21H,16-17H2;1H/q+1;/p-1
• InChI key: XMPWFKHMCNRJCL-UHFFFAOYSA-M

Description

Application

Used for electrolytic polarization of Zn

Studied for potential antitumor activity

Reactant for synthesis of:

• Keto halides for sequential azidation and intramolecular Schmidt reactions
• Cycloporpylidenemethylarylethynynes
• Dipeptides containing azabicyclo[3.1.0]hexane

Reactant for hydroalkynylation

Wittig reagent

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves