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131903

Sigma-Aldrich

Tetraethyl orthosilicate

reagent grade, 98%

Synonym(s):

Orthosilicic acid tetraethyl ester, Silicon tetraethoxide, TEOS, Tetraethoxysilane, Tetraethoxysilicon(IV), Tetraethyl silicate

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About This Item

Linear Formula:
Si(OC2H5)4
CAS Number:
Molecular Weight:
208.33
Beilstein:
1422225
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

grade

reagent grade

Quality Level

vapor density

7.2 (vs air)

vapor pressure

<1 mmHg ( 20 °C)

Assay

98%

form

liquid

refractive index

n20/D 1.382 (lit.)

bp

168 °C (lit.)

density

0.933 g/mL at 20 °C (lit.)

SMILES string

CCO[Si](OCC)(OCC)OCC

InChI

1S/C8H20O4Si/c1-5-9-13(10-6-2,11-7-3)12-8-4/h5-8H2,1-4H3

InChI key

BOTDANWDWHJENH-UHFFFAOYSA-N

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General description

Tetraethyl orthosilicate(TEOS) is a colorless liquid alkoxide widely used as precursor to deposition of silicon dioxide (SiO2) thin films. It is also utilized in hydrogels, nanoparticle-based drug delivery systems, and chemical crosslinking of polymers.

Application

Tetraethyl orthosilicate can be used:
  • As an anti-solvent to fabricate efficient perovskite layer for inverted planar solar cells with enhanced power conversion efficiency and reproducibility. TEOS helps to achieve high-quality perovskite films with reduced density of defects, and thus slower carrier recombination.
  • As a sol-gel precursor to synthesize SiO2-TiO2 anti-reflective self-cleaning coatings for solar cells.
  • To fabricate nano silica functionalized crosslinked hybrid membranes for proton exchange membrane fuel cell applications. These membranes have better proton conductivity and thermal stability.
  • To prepare poly(vinylidene fluoride)/TEOS matrix separator to enhance the performance of Li-ion batteries. The separator exhibits excellent electrolyte retention and wettability.

Commonly used as a precursor to prepare xerogel
Will interact with dodecylamine in the formation of intercalation compounds of H+-magadiite and used in a study of mixed-metal bioactive glasses.

Features and Benefits

  • Excellent adhesion on substrates
  • Uniform film deposition
  • Cross-linker to introduce polymer strands into hydrogel

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point(F)

113.0 °F - closed cup

Flash Point(C)

45 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Articles

Silica is a very popular inorganic nanomaterial used in a wide range of applications including fillers for rubber, catalyst supports, separation media, carriers in food and agriculture, and abrasive/anticaking agents in cosmetics. It is also widely believed to be an important material for biomedical applications for following reasons.

Hybrid organic-inorganic sol-gel materials containing silica were first called “ORMOSILs” in 1984.

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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