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928291

Sigma-Aldrich

Platinum(IV) oxide ChemBeads

Synonym(s):

Adam’s catalyst, NSC 402624, Platinic oxide, Platinum dioxide

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About This Item

Linear Formula:
PtO2
CAS Number:
UNSPSC Code:
12352303
NACRES:
NA.21

form

solid

Quality Level

extent of labeling

~5 wt. % loading of catalyst

SMILES string

[Pt]OO

InChI

1S/2O.Pt

InChI key

YKIOKAURTKXMSB-UHFFFAOYSA-N

Application

Platinum(IV) oxide has been used for the reduction of citernyl bromide to form (S)-3,7-imethyloctylbromide.Catalyst for hydrogenation of various functional groups with minimal hydrogenolysis problems; used as dehydrogenation catalyst; used for selective oxidation of primary alcohols.Catalyst for: Hydrohydrazination reactions, Oxidation of sugars, Low-temperature oxidation of carbon monoxide, Oxygen reduction reaction, Hydrogenation reactions, Hydrogenolysis of the cyclopropyl group into an isopropyl group, Hydroxycyclopropanation reactions.


ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

Learn more about ChemBeads products

For larger scale uses, product also available in powdered form (206032)

Pictograms

Flame over circleHealth hazard

Signal Word

Danger

Hazard Statements

Hazard Classifications

Carc. 1B Inhalation - Ox. Sol. 1

Storage Class Code

5.1A - Strongly oxidizing hazardous materials

WGK

WGK 2


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